| 850804-97-6

• CAS: 850804-97-6
• 化学式: C₁₁H₁₈CrO₄Sb₂
• 分子量: 509.758
• InChiKey: LIRCFUVRYSNJIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetracarbonylnorbornadienchrom 、 1,3-bis(dimethylstibino)propane 以 乙醇 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  The transition metal carbonyl complexes of 1,3-bis(di-R-stibino)propanes (R=Me or Ph)

  摘要：

  The synthesis and characterisation of complexes of two distibinopropanes R2Sb(CH2)(3)SbR2(R = Me or Ph) with a variety of metal carbonyls is described. These include cis-[M(CO)(4){R2Sb(CH2)(3)SbR2}] (M = Cr, Mo or W), [{Fe(CO)(4)}(2){mu-R2Sb(CH2)(3)SbR2}], [{Ni(CO)(3)}(2){mu-R2Sb(CH2)(3)SbR2}], [Co-2(CO)(6){Ph2Sb(CH2)(3)SbPh2}], [Co-2(CO)(4){Me2Sb(CH2)(3)SbMe2}(3)][Co(CO)(4)](2) and [Mn-2(CO)(8)-{Ph2Sb(CH2)(3)SbPh2}]. The complexes have been characterised by analysis, mass spectrometry, IR and multinuclear NMR spectroscopy as appropriate. Comparison of the spectroscopic data on these complexes with those of other stibine complexes and with complexes of Group 16 ligands has been used to establish the relative electronic properties of the distibines. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.12.020