Cu2Cl2(diacetylmonooxime 1'-phthalazinylhydrazone(-H))2 | 1239614-68-6

• 英文名称: Cu2Cl2(diacetylmonooxime 1'-phthalazinylhydrazone(-H))2
• CAS: 1239614-68-6
• 化学式: C₂₄H₂₄Cl₂Cu₂N₁₀O₂
• 分子量: 682.518
• InChiKey: SMBQCRQEQMFWTA-NJNIBWCSSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diacetylmonooxime 1'-phthalazinyl hydrazone 、 copper dichloride 以 甲醇 为溶剂， 生成 Cu2Cl2(diacetylmonooxime 1'-phthalazinylhydrazone(-H))2
  参考文献：
  名称：

  1′-Phthalazine hydrazone of diacetyl monooxime and its complexes with transition metals: Physicochemical and theoretical study

  摘要：

  1'-Phthalazine hydrazone of diacetyl monooxime and its Cu(II) and Ni(II) complexes were synthesized. The acid-base properties of the hydrazone were potentiometrically and spectrophotometrically studied, and quantum-chemical calculations of the ionization constants and the energies of possible tautomeric forms and conformations were performed. Complexes of copper(II) prepared by the reaction of the hydrazone with copper(II) acetate, chloride, and bromide were shown to have the dimeric structure with the bidentatebridging N-O-groups of the oxime fragment, whereas the copper(II) complex prepared from copper(II) nitrate, forms the dimer via the endocyclic nitrogen atoms of the phthalazine fragment.

  DOI：

  10.1134/s1070363210030217

文献信息

• 1-Hydrazinophthalazine based hydrazones and their transition metal complexes: Structure and biological activity
  作者：V. A. Kogan、S. I. Levchenkov、L. D. Popov、I. A. Shcherbakov

  DOI：10.1134/s1070363209120354

  日期：2009.12

  Structure, tautomeric rearrangements, acid-base properties and complex formation ability of 1-hydrazinophthalazine hydrazones and their coordination compounds with transition metals are considered. The main factors influencing the structure and physicochemical properties of the complexes, biological activity of phthalazine hydrazones and their complexes are discussed.