fac-[ReCl(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)] | 1240381-21-8

• 英文名称: fac-[ReCl(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)]
• CAS: 1240381-21-8
• 化学式: C₃₁H₃₀ClN₂O₃P₂Re
• 分子量: 762.198
• InChiKey: XYIDRIPBJOKCSS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 fac-[ReH(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)] 以 二氯甲烷 为溶剂， 以86%的产率得到fac-[ReCl(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)]
  参考文献：
  名称：

  New complexes of the fac-{(CO)3Re+} fragment bearing a diaminediphosphine ligand

  摘要：

  The mono- and binuclear hydride compounds fac-[ReH(CO)(3)L) (1a) and [(ReH(CO)(4)}(2)(mu-L)] (1b) have been prepared by reaction of [ReH(CO)(5)] with Ph2PN(CH3)(CH2)(2)N(CH3)PPh2 (L) under UV light. Protonation reactions of the hydride compound la with equimolar amounts of HSO3CF3 or HCl yielded the triflato or the chlorido compounds fac-[Re(OSO2CF3)(CO)(3)L) (2) and fac-[ReCl(CP)(3)L] (3), respectively. The compounds have been characterised by elemental analysis, IR and NMR spectroscopic data, and mass spectrometry. Their structures have been confirmed by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.013