[((C6H5)2P(S)NC(NH)CH3-S,N)(η3-C3H5)palladium(II)] | 362517-96-2

• 英文名称: [((C6H5)2P(S)NC(NH)CH3-S,N)(η3-C3H5)palladium(II)]
• CAS: 362517-96-2
• 化学式: C₁₇H₁₉N₂PPdS
• 分子量: 420.811
• InChiKey: TWEGQJXMUGSRLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 (1-Aminoethylideneamino)-diphenyl-sulfidophosphanium 在 potassium t-butoxide 作用下， 以 四氢呋喃 为溶剂， 生成 [((C6H5)2P(S)NC(NH)CH3-S,N)(η3-C3H5)palladium(II)]
  参考文献：
  名称：

  Bridge cleavage of transition metal dimers by chelating S,N ligands. X-ray crystal structure of [Pd{SPPh2NC(NH2)NH-S,N}(η3-C3H5)]

  摘要：

  Deprotonation of the N-thiophosphoryl compounds Me2P(S)N=C(NH2)(2) (HL1), Ph2P(S)N=C(Me)(NH2) (HL2) or Ph2P(S)N=C(NH2)(2), (HL3) using potassium t-butoxide in thf, followed by treatment with [Rh(mu -Cl)(eta (4)-cod)](2) (cod = 1,5-cis,cis-cyclooctadiene), [Pd(mu -Cl)(eta (3)-C3H5)](2) or [RhCl(mu -Cl)(eta (5)-C5Me5)](2) affords [Rh(L-n-S,N)(eta (4)-cod)] 1-3, [Pd(L-n-S,N)(eta (3)-C3H5)] 4-6 and [RhCl(L-n-S,N)(eta (5)-C5Me5)] 7-9, respectively. The (L-n)- anions form six-membered S,N chelate rings at the metal centre, in a manner analogous with beta -diketonates and imidodiphosphinates. The complexes 1-9 have been characterised spectroscopically and by single crystal X-ray diffraction for [Pd(L-3-S,N)(eta (3)-C3H5)] 6. The molecular structure of 6 confirms S,N chelation of the (L-3)(-) anion to give a palladacycle adopting a half boat conformation. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00738-0