[(3Me-sal)Zn(μ-OtBu)]2 | 701912-08-5

• 英文名称: [(3Me-sal)Zn(μ-OtBu)]2
• CAS: 701912-08-5
• 化学式: C₃₀H₄₆N₂O₄Zn₂
• 分子量: 629.486
• InChiKey: YSFOIEFOJSCFJT-QGGWCOBGSA-L

反应信息

• 作为反应物：
  描述：

  [(3Me-sal)Zn(μ-OtBu)]2 以 neat (no solvent) 为溶剂， 生成 [(3-Me-sal)Zn(OH)]2
  参考文献：
  名称：

  Defect-Induced Acceleration of a Solid-State Chemical Reaction in Zinc Alkoxide Single Crystals

  摘要：

  A family of dinuclear (salicylaldimato)zinc(mu(2)-alkoxide) complexes show unusual behavior, decomposing to olefins and the corresponding mu(2)-hydroxide complexes under very mild conditions in the solid state. The reaction in homogeneous solution is, on the other hand, not observable, even at elevated temperatures over extended periods of time. The reaction in the solid state occurs preferentially on one crystallographic face and displays kinetics characteristic of polymorphic transformations in single crystals.

  DOI：

  10.1021/ic030341o
• 作为产物：
  描述：

  bis(bis(trimethylsilyl)amido)zinc(II) 、 3-methylsalicylaldimine 、 叔丁醇 以 四氢呋喃 为溶剂， 以68%的产率得到[(3Me-sal)Zn(μ-OtBu)]2
  参考文献：
  名称：

  Defect-Induced Acceleration of a Solid-State Chemical Reaction in Zinc Alkoxide Single Crystals

  摘要：

  A family of dinuclear (salicylaldimato)zinc(mu(2)-alkoxide) complexes show unusual behavior, decomposing to olefins and the corresponding mu(2)-hydroxide complexes under very mild conditions in the solid state. The reaction in homogeneous solution is, on the other hand, not observable, even at elevated temperatures over extended periods of time. The reaction in the solid state occurs preferentially on one crystallographic face and displays kinetics characteristic of polymorphic transformations in single crystals.

  DOI：

  10.1021/ic030341o