[Rh(III)(N-(pyridine-2-yl)morpholine-4-carbothioamide)2Cl2]Cl*(ethanol) | 949153-01-9

• 英文名称: [Rh(III)(N-(pyridine-2-yl)morpholine-4-carbothioamide)2Cl2]Cl*(ethanol)
• CAS: 949153-01-9
• 化学式: C₂H₆O*C₂₀H₂₆Cl₂N₆O₂RhS₂*Cl
• 分子量: 701.931
• InChiKey: KPNUXFXSMBCVJZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙醇 、 氯化铑(三水) 、 N-(pyridine-2-yl)mrpholine-4-carbothioamide 以 乙醇 为溶剂， 以69%的产率得到[Rh(III)(N-(pyridine-2-yl)morpholine-4-carbothioamide)2Cl2]Cl*(ethanol)
  参考文献：
  名称：

  Synthesis and spectroscopic investigations of Rh(III) and Pd(II) complex compounds with N-(pyridine-2-yl)morpholine-4-carbothioamide

  摘要：

  The present paper describes the synthesis and spectral properties of Rh(III) and Pd(II) coordination compounds with N-(pyridine-2yl)morpholine-4-carbothioamide (PMCTA). The compounds have the general composition [RhL2CI2]Cl C2H5OH (1), [PdL2]Cl-2 (2), [PdL2ClO4,), - (C3H6O)-C-2 (2a), [PdLCI,] - 2H(2)O (3). All complexes were characterized by elemental analysis, IR, H-1 NMR, 13 C NMR, XPS and UV-Vis spectra. It has been shown that PMCTA behaves as a bidentate (N,S)-ligand, forming six membered metallocycles and coordinating to the metal ion through the carbothioamide sulfur atom and the pyridine nitrogen atom. The UV-Vis spectra suggest that the Pd(II) complexes are square planar, while the Rh(III) complex has an octahedral geometry. The molecular structure of the Pd(II) complex with PMCTA (M:L = 1:2) was determined by single-crystal X-ray diffraction. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.01.042