| 134621-03-7

• CAS: 134621-03-7
• 化学式: C₄₀H₃₃ClOP₂RuS₂
• 分子量: 792.304
• InChiKey: JSNDQNGFENCQLU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  Ru(CH=CH2)Cl(CO)(triphenylphosphine)2 在 二硫化碳 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  The formation of alkenedithiocarboxylate and alkenecarboxylate ligands by insertion of CS2 and CO2 into ruthenium(II)alkenyl bonds

  摘要：

  The unsaturated alkenyl complexes Ru(CO)Cl(RC=CHR')(PPh3)2 react with CS2 and CO2 to give Ru(CO)(Cl(S2CRC=CHR')(PPh3)2 and Ru(CO)Cl(O2CRC= CHR')(PPh3)2 complexes, respectively. The products are hexacoordinated-ruthenium (II) complexes containing alkenedithiocarboxylate or alkenecarboxylate ligands eta-2-coordinated to metal. In these reactions CS2 and CO2 insert into ruthenium-alkenyl bonds to form new chelated ligands. The structures of products and the nature of the alkene-dithiocarboxylate and alkenecarboxylate ligands have been established from spectroscopic data (IR, H-1 and P-31 NMR).

  DOI：

  10.1016/0022-328x(91)86387-6