{(ruthenium)2H(carbonyl)5(μ-(MeO)2PN(Et)P(OMe)2)2} hexafluorophosphate | 145631-93-2

• 英文名称: {(ruthenium)2H(carbonyl)5(μ-(MeO)2PN(Et)P(OMe)2)2} hexafluorophosphate
• CAS: 145631-93-2
• 化学式: C₁₇H₃₅N₂O₁₃P₄Ru₂*F₆P
• 分子量: 946.47
• InChiKey: GAESTHHIYPRUEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(ruthenium)2H(carbonyl)5(μ-(MeO)2PN(Et)P(OMe)2)2} hexafluorophosphate 在 CS₂ 作用下， 以 1,2-二氯乙烷 为溶剂， 生成 {(ruthenium)2(μ-η2-SCHS)(carbonyl)4(μ-(MeO)2PN(Et)P(OMe)2)2} hexafluorophosphate
  参考文献：
  名称：

  Synthesis of three-, four-, and five-membered dimetalloheterocyclic compounds by reaction of the hydride [Ru2H(CO)5μ-(RO)2PN(Et)P(OR)22][PF6] (R = Me or Pri) with unsaturated systems of the type XY and X′Y′Z′. Crystal structures of representative examples of the three types of products

  摘要：

  DOI：

  10.1016/0022-328x(90)80263-y
• 作为产物：
  描述：

  在 sodium acetate 作用下， 以 乙醇 、 二氯甲烷 、 水 为溶剂， 生成 {(ruthenium)2H(carbonyl)5(μ-(MeO)2PN(Et)P(OMe)2)2} hexafluorophosphate
  参考文献：
  名称：

  Protonation of diphosphazane ligand-bridged derivatives of diruthenium nonacarbonyl by protic acids with co-ordinating and non-co-ordinating conjugate bases

  摘要：

  Protonation of the diphosphazane ligand-bridged derivatives [Ru2(mu-CO)(CO)4{mu-(RO)2PN(Et)P(OR)2}2] (R = Me or Pr(i)) by HBF4 or HPF6 leads to the formation of the cationic hydrido products [Ru2H(CO)5{mu-(RO)2PN(Et)P(OR)2}2]+ in which the hydride ligand is co-ordinated terminally. On the other hand, protonation of these species with strong protic acids HA having conjugate bases A- with co-ordinating properties [A- = Cl-, Br-, NO3-, FB(O)OH- or CF3CO2-] gives rise to products of the type [Ru2A(CO)5{mu-(RO)2PN(Et)P(OR)2}2]+ and/or [Ru2(mu-A)(CO)4{mu-(RO)2PN(Et)P(OR)2}2]+. Weak acids HA (A- = SPh- or HCO3-) also afford these types of products but the presence of a strong acid such as HPF6 is necessary. The structures of two of the products [Ru2{mu-OB(F)OH}(CO)4{mu-(PriO)2PN(Et)P(OPri2}2]BF4 and [Ru2(mu-SPh)(CO)4{mu-(MeO)2PN(Et)P(OMe)2}2]PF6 have been established by X-ray crystallography and are discussed as is the fluxional behaviour of the hydrido species [Ru2H(CO)5{mu-(RO)2PN(Et)P(OR)2}2]+.

  DOI：

  10.1039/dt9920002629