| 400720-23-2

• CAS: 400720-23-2
• 化学式: C₄₄H₄₂ClFeOsP₂*F₆P
• 分子量: 1059.23
• InChiKey: IPSJQGNVOWVGPA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 tert-butylammonium hexafluorophosphate(V) 以 丙酮 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  Iron(II) versus osmium(II) oxidation in 1,1′-bis(diorganophosphino)ferrocene–osmium(II) complexes

  摘要：

  The compounds [(Cym)OsCl(dxpf)](PF6), Cym = p-cymene and dxpf: 1,1'-bis(diphenylphosphino)ferrocene (dppf), 1, 1'-bis(diethylphosphino)ferrocene (depf) or 1,1'-bis(diisopropylphosphino)ferrocene (dippf), were synthesized and characterized by NMR (H-1, P-31) and, in the case of [(Cym)OsCl(dppf](PF6), by X-ray structure analysis of the acetonitrile solvate. EPR and UV-vis spectroelectrochemistry indicate the formation of an osmium(II)-ferrocenium species on reversible one-electron oxidation. The second oxidation and the reduction are electrochemically irreversible. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00898-1