[bis(diethylenetriamine)copper(II)][Ph2Sn(IV)Cl4] | 1017624-68-8

• 英文名称: [bis(diethylenetriamine)copper(II)][Ph2Sn(IV)Cl4]
• CAS: 1017624-68-8
• 化学式: C₈H₂₆CuN₆*C₁₂H₁₀Cl₄Sn
• 分子量: 684.614
• InChiKey: MSUJTDOKVBLFND-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  [copper(II)(diethylenetriamine)2]Cl2 、 二苯基二氯化锡 以 甲醇 、 四氯化碳 为溶剂， 以35%的产率得到[bis(diethylenetriamine)copper(II)][Ph2Sn(IV)Cl4]
  参考文献：
  名称：

  A route to novel stable salts containing transition and main group metals

  摘要：

  Novel salts of the type [Cu(Dien)(2)][Bu3SnCl3], [Cu(Dien)(2)][Ph2SnCl4], and [Cu(Dien)(2)][SnCl6] (Dien-diethylenetriamine) were prepared by the reaction of [Cu(Dien)(2)]Cl-2 with Bu3SnCl, Ph2SnCl2 and SnCl4 in MeOH in a 1 : 1 ratio, respectively, and characterized, by elemental analyses, electronic, IR and ESR spectroscopy, magnetic susceptibility, electrochemistry, and conductivity measurements. The results revealed that the compounds are 1 : 1 electrolytes and the Cu2+ ion is paramagnetic in the octahedral field. The complexes exhibit a single-electron redox couple.

  DOI：

  10.1134/s1070328407050090