5-tert-butyl-3-morpholinometyl-salicylaldiminepalladium(II) | 1220915-01-4

• 英文名称: 5-tert-butyl-3-morpholinometyl-salicylaldiminepalladium(II)
• CAS: 1220915-01-4
• 化学式: C₂₈H₃₉Cl₂N₂O₂Pd
• 分子量: 612.956
• InChiKey: WUDQEXPKVLRBPW-JOURZYLGSA-K

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 5-tert-butyl-3-morpholinometyl-salicylaldimine 以 乙腈 为溶剂， 以93%的产率得到5-tert-butyl-3-morpholinometyl-salicylaldiminepalladium(II)
  参考文献：
  名称：

  Synthesis and characterization amino-salicylaldimine palladium-based complexes and their Suzuki coupling reaction study

  摘要：

  A series of amino-salicylaldimine ligands, 5-R-3-morpholinomethyl-salicylaldimine (R = t-Bu, CH3, Br) have been synthesized and structurally analyzed. These tridentate ligands add to palladium (11) to give high yields of air-stable complexes that are characterized by IR, H-1 NMR and elemental analysis. Crystal structure details of complex I are presented. These Pd (11) complexes with amino-salicylaldimine ligands are versatile and efficient Suzuki catalysts towards cross-coupling of a variety of aryl chlorides with phenylboronic acid using DMF as solvent. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.06.031