bis[bis(mercaptoethane)diazacycloheptane nickel(II)] chloronickel(II) chloride | 738584-87-7

• 英文名称: bis[bis(mercaptoethane)diazacycloheptane nickel(II)] chloronickel(II) chloride
• CAS: 738584-87-7
• 化学式: C₁₈H₃₆ClN₄Ni₃S₄*Cl
• 分子量: 683.751
• InChiKey: QUHDTDMDVUWVTN-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  Ni(bme-dach) 、 nickel(II) chloride hexahydrate 以 甲醇 为溶剂， 以60%的产率得到bis[bis(mercaptoethane)diazacycloheptane nickel(II)] chloronickel(II) chloride
  参考文献：
  名称：

  The Construction of (N ₂ S ₂ )Ni−Pd Clusters: A Slant‐Chair, a Basket and a C ₄ ‐Paddlewheel Structure

  摘要：

  AbstractIn pursuit of an analogy between bidentate diphosphane ligands and cis‐dithiolato nickel complexes, the easily prepared [bis(mercaptoethane)diazacycloheptane]nickel complex, Ni‐1′, has been treated with PdII and NiII sources. With the latter, trinickel species are observed with typical slant‐chair structures; for palladium(II) chloride, a basket‐type structure is realized in which the floor of the basket is a PdS4 unit and the sides are N2S2 units. One chloride atom is held within the basket at a Pd···Cl distance of 3.26 Å. With Pd(NO3)2 as a palladium source, a hexanuclear aggregate in the form of a C4‐paddlewheel structure is obtained. In this structure, the N2S2Ni complex serves as a bidentate ligand which bridges two Pd2+ cations at a distance of 3.132 Å. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200300675