(cyclopentadienyl)2Ti(IV)Cl(water)(1+) | 852570-46-8

• 英文名称: (cyclopentadienyl)2Ti(IV)Cl(water)(1+)
• 英文别名: Cp2TiCl(H2O)(1+)
• CAS: 852570-46-8
• 化学式: C₁₀H₁₂ClOTi
• 分子量: 231.538
• InChiKey: KWIULASVKXWUFY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯二茂钛 、 水 在 sodium chloride 作用下， 以 乙醇 、 水 为溶剂， 生成 (cyclopentadienyl)2Ti(IV)Cl(water)(1+)
  参考文献：
  名称：

  Electrochemical evaluation of the interaction between antitumoral titanocene dichloride and biomolecules

  摘要：

  Electrochemical investigation of the interaction between titanocene dichloride and several biomolecules, i.e., human and bovine serum albumin (HSA and BSA), and single-strand and double-strand deoxyribonucleic acid (ss- and ds-DNA) is reported. The addition of biomolecules to a hydroalcoholic solution of TiCp2Cl2 was followed by a decrease in the Ti(IV)/Ti(III) reduction peak current, due to the formation of adducts with lower diffusion coefficients. Qualitative analysis of the data reveals that titanocene dichloride has a higher affinity for proteins than for nucleic acids. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.06.022