dichloro-([1α,4α,5α7R]-[5-(diphenylarsino)-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene-As(5),P(7)])palladium(II) | 178882-58-1

• 英文名称: dichloro-([1α,4α,5α7R]-[5-(diphenylarsino)-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene-As(5),P(7)])palladium(II)
• CAS: 178882-58-1
• 化学式: C₂₆H₂₆AsCl₂PPd
• 分子量: 621.714
• InChiKey: QKLQILGCMHEMDP-MTJMGRNBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 ((S)-1-[1-(dimethylamino)ethyl]naphtyl-C(2),N)-((1α,4α,5α7R)-[5-(diphenylarsino)-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene-As(5),P(7)])palladium(II) perchlorate 以 丙酮 为溶剂， 以91%的产率得到dichloro-([1α,4α,5α7R]-[5-(diphenylarsino)-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene-As(5),P(7)])palladium(II)
  参考文献：
  名称：

  Asymmetric Synthesis of a (P-Chiral) As−P Bidentate Ligand via an Organopalladium Complex Promoted Asymmetric Diels−Alder Reaction between Ph₂AsCHCH₂ and 1-Phenyl-3,4-dimethylphosphole

  摘要：

  Convenient access to the enantiomerically pure rigid bidentate ligand (-)-[5-(diphenylarsino)-2,3 -dimethyl-7-phenyl-7(S)-phosphabicyclo[2.2.1]hept-2-ene is established via an asymmetric [4 + 2] cycloaddition between diphenylvinylarsine and 1-phenyl-3,4-dimethylphosphole using the chiral organopalladium(II) complex containing ortho-metalated dimethyl[1-(2-naphthyl)ethyl]amine as the reaction promoter. The absolute configurations of the four newly generated stereocenters have been assigned by single-crystal X-ray analysis.

  DOI：

  10.1021/om9600351