Cp2Mo2Fe(CO)7(μ3-Se) | 159509-16-7

• 英文名称: Cp2Mo2Fe(CO)7(μ3-Se)
• CAS: 159509-16-7
• 化学式: C₁₇H₁₀FeMo₂O₇Se
• 分子量: 652.949
• InChiKey: IPPNUWGHFNZTHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  十二羰基三锇 、 Cp2Mo2Fe(CO)7(μ3-Se) 以 甲苯 为溶剂， 以26%的产率得到
  参考文献：
  名称：

  Synthesis, characterisation and nonlinear optical properties of tetrahedral clusters Cp2Mo2ME(CO)7, (M=Fe, Ru, Os; E=S, Se)

  摘要：

  A set of new chalcogen-bridged mixed metal clusters, Cp2Mo2M(mu(3)-E)(CO)(7), (M = Fe, Ru, Os; E = S, Se) have been synthesised and characterised by IR and NMR spectroscopy, and structures of Cp2Mo2Ru(mu(3)-Se)(CO)(7) and Cp2Mo2Os(mu(3)-Se)(CO)(7) have been established by single crystal X-ray diffraction methods. The nonlinear optical properties of these clusters were investigated through the Z-scan technique, using 35 ps laser pulses at 532 nm. We report large refractive third order nonlinearity for these clusters indicating their promise for optical limiting applications. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00810-9
• 作为产物：
  描述：

  selenium 、 cyclo-μ3-Sulfido-(tricarbonyleisen)bis[dicarbonyl(η-cyclopentadienyl)molybdaen](2Fe-Mo,Mo-Mo) 以 苯 为溶剂， 以0%的产率得到Cp2Mo2Fe(CO)7(μ3-Se)
  参考文献：
  名称：

  Synthesis, characterisation and nonlinear optical properties of tetrahedral clusters Cp2Mo2ME(CO)7, (M=Fe, Ru, Os; E=S, Se)

  摘要：

  A set of new chalcogen-bridged mixed metal clusters, Cp2Mo2M(mu(3)-E)(CO)(7), (M = Fe, Ru, Os; E = S, Se) have been synthesised and characterised by IR and NMR spectroscopy, and structures of Cp2Mo2Ru(mu(3)-Se)(CO)(7) and Cp2Mo2Os(mu(3)-Se)(CO)(7) have been established by single crystal X-ray diffraction methods. The nonlinear optical properties of these clusters were investigated through the Z-scan technique, using 35 ps laser pulses at 532 nm. We report large refractive third order nonlinearity for these clusters indicating their promise for optical limiting applications. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00810-9

文献信息

• Thermolysis of Fe3(CO)9(μ3-Se)(μ3-E) (E = S, Te) with Cp2Mo2(CO)6 and formation of new mixed-chalcogenide, mixed Fe-Mo carbonyl clusters. Crystal structures of Cp2Mo2Fe2(CO)6(μ3-Se)2(μ4-Te), Cp2Mo2Fe2(CO)7(μ3-Se)(μ3-Te) and Cp2Mo2Fe2(CO)6(μ3-S)(μ3-Se)(μ4-Se)
  作者：Pradeep Mathur、Sanjukta Ghose、Md. Munkir Hossain、C.V.V. Satyanarayana、Mary F. Mahon

  DOI：10.1016/s0022-328x(97)00195-2

  日期：1997.9

  reaction of Fe3(CO)9(μ3-Se)(μ3-Te) with Cp2Mo2(CO)6 in benzene yielded the new mixed-metal, mixed trichalcogenide clusters Cp2Mo2Fe2(CO)6(μ3-Se)(μ3-Te)(μ4-Te) (2a), Cp2Mo2Fe2(CO)6(μ3-Te)2(μ4-Se) (2b) and Cp2Mo2Fe2(CO)6(μ3-Se)2(μ4-Te) (3a), Cp2Mo2Fe2(CO)6(μ3-Se)(μ3-Te)(μ4-Se) (3b) as well as the dichalcogenide cluster Cp2Mo2Fe2(CO)7(μ3-Se)(μ3-Te) (8). Similarly, the thermolysis of Fe3(CO)9(μ3-S)(μ3-Se) with

  Fe的热分解反应3（CO）9（μ 3 -Se）（μ 3 -Te）再用Cp 2沫2（CO）6苯得到的新的混合金属，混合trichalcogenide簇的Cp 2沫2的Fe 2（ CO）6（μ 3 -Se）（μ 3 -Te）（μ 4 -Te）（图2a）中，Cp 2沫2的Fe 2（CO）6（μ 3 -Te）2（μ4 -Se）（图2b）1和Cp 2沫2的Fe 2（CO）6（μ 3 -Se）2（μ 4 -Te）（图3a）中，Cp 2沫2的Fe 2（CO）6（μ 3 -Se ）（μ 3 -Te）（μ 4 -Se）（图3b），以及所述二硫属化物簇的Cp 2沫2的Fe 2（CO）7（μ 3 -Se）（μ 3-Te）（8）。类似地，Fe的热解3（CO）9（μ 3 -S）（μ 3 -Se）再用Cp 2沫2（CO）6苯得到新的混合金属，混合trichalcogenide簇的Cp 2沫2的Fe 2（CO）6（μ 3
• Metal substitution reaction in the cluster (μ-H)2Fe3(μ3-Se) (CO)9—II. Crystal and molecular structure of [FeW2(μ3-Se) (CO)7Cp2] and [FeMoW(μ3-Se) (CO)7Cp2] (Cp= η5-C5H5)
  作者：Sergei N. Konchenko、Alexander V. Virovets、Sergei V. Tkachev、Nina V. Podberezskaya

  DOI：10.1016/0277-5387(96)00267-7

  日期：1997.1

  The sequential substitution of two Fe(CO)3 groups in [(μ-H)2Fe3(μ3-Se) (CO)9] with isolobal fragments CpW(CO)2 (the first stage) and CpMo(CO)2 (the second stage) has been shown to result in the title heterotrimetal cluster [FeMoW(μ3-Se) (CO)7Cp2]. Its structure and the structure of its [FeW2(μ3-Se) (CO)7Cp2] analog obtained previously have been determined by X-ray analysis.

  2的Fe（CO）的顺序置换3组[（μ-H）2的Fe 3（μ 3 -Se）（CO）9 ]与等瓣片段CPW（CO）2（第一阶段）和合物CPMo（CO）2（第二级）已被证明导致标题heterotrimetal簇[FeMoW（μ在3 -Se）（CO）7的CP 2 ]。它的结构和它的的结构[FEW 2（μ 3 -Se）（CO）7的CP 2 ]模拟获得的先前已通过X-射线分析测定。
• Synthesis and characterisation of cis and trans isomers of the mixed chalcogen clusters Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Se) and Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Te)
  作者：Pradeep Mathur、Saurav Chatterjee、Sanjukta Ghose、Mary F. Mahon

  DOI：10.1016/s0022-328x(99)00285-5

  日期：1999.9

  The reaction of Fe-2(CO)(6)(mu-SSe) and Cp2Mo2(CO)(4) in benzene at room temperature for 2 h, yielded the new isomeric mixed-metal, mixed-dichalcogenide clusters trans-Cp2Mo2Fe2(CO)(8)(mu(3)-S)(mu(3)-Se) (1) and cis-Cp2Mo2Fe2(Co)(8)(mu(3)-S)(mu(3)-Se) (4). The new mixed-metal clusters 1 and 4 could also be obtained when Fe-3(CO)(9)(mu(3)-S)(mu(3)-Se) and Cp2Mo2(CO)(6) were heated at 65 degrees C in benzene for 36 h. Similarly, the room-temperature reaction of Fe-2(CO)(6)(mu-STe) with Cp2Mo2(CO)(4) in benzene for 2 h and the thermolytic reaction of Fe-3(CO)(9)(mu(3)-S)(mu(3)-Te) with Cp2Mo2(CO)(6) in benzene for 36 h afforded the new isomeric clusters trans-Cp2Mo2Fe2(CO)(8)(mu(3)-S)(mu(3)-Te) (9) and cis-Cp2Mo2Fe2(CO)(8)(mu(3)-S)(mu(3)-Te) (11). The new clusters have been characterised by IR and by H-1-, Se-77-, Te-125-NMR spectroscopy. Clusters 1 and 4 have also been structurally characterised by single-crystal X-ray diffraction methods. (C) 1999 Elsevier Science S.A. All rights reserved.