[Cd3(4,6-dimethylpyrimidine-2-thione(1-))3(2,2-bipyridine)3Br2] | 1202878-34-9

• 英文名称: [Cd3(4,6-dimethylpyrimidine-2-thione(1-))3(2,2-bipyridine)3Br2]
• CAS: 1202878-34-9
• 化学式: C₄₄H₄₄Br₂Cd₃N₁₂S₄
• 分子量: 1366.22
• InChiKey: KYXXPFDGZNSJRI-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 cadmium(II) bromide tetrahydrate 、 Cd(4,6-dimethylpyrimidine-2-thione(1-))2 以 N,N-二甲基甲酰胺 为溶剂， 以94%的产率得到[Cd3(4,6-dimethylpyrimidine-2-thione(1-))3(2,2-bipyridine)3Br2]
  参考文献：
  名称：

  Synthetic procedures and structural features of new di- and tri-nuclear chelate compounds of Cd(II) with sulfur and nitrogen donor ligands

  摘要：

  Cd(dmpymt)(2) reacts with CdCl2, CdBr2 center dot 4H(2)O, Cdl(2), 2,2'-bipyridine and 1,10-phenanthroline to give the dimeric chelates [Cd(dmpymt)(bpy)Cl](2) and [Cd(dmpymt)(phen)Cl](2), as well as the tri-nuclear complexes [Cd-3(dmpymt)(4)(bpy)(2)Br-2] and [Cd-3(dmpymt)(4)(bpy)(2)I-2] (dmpymtH=4,6-dimethylpyrimidine-2-thione; bpy = 2,2'-bipyridine; phen = 1,10-phenantroline). In all complexes the Cd(II) centers present the coordination number six. The new compounds are examples of the managing of the final aggregation state of thiolate metal complexes by introducing co-ligands to block specific coordination sites of the metal center. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.08.018