| 160294-03-1

• CAS: 160294-03-1
• 化学式: C₅₄H₄₅CuP₃S₃*F₆P
• 分子量: 1091.58
• InChiKey: CNHRVFGANUOODN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  三苯基瞵硫 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and solution multinuclear magnetic resonance studies of homoleptic copper(I) complexes of sulfur, selenium and tellurium donor ligands

  摘要：

  The complexes [CuL4][O3SCF3] (L = Me2S, Me2Se, Me2Te, Ph2S, Ph2Se or Ph2Te) and [Cu(L-L)2]PF6 [L-L = RE(CH2)2ER (E = S or Se, R = Me or Ph); RE(CH2)3ER (E = S, Se or Te; R = Me or Ph)] have been prepared and characterised by analysis, IR, and in particular multinuclear NMR spectroscopy (H-1, Se-77, Te-125 and Cu-63). Variable-temperature NMR studies have been used to probe various exchange processes occurring in solution. For a limited number of complexes Cu-63 NMR resonances have been observed, the first examples from Group 16 donor complexes.

  DOI：

  10.1039/dt9940003225