molybdenum hexacarbonyl | 25941-10-0

• 英文名称: molybdenum hexacarbonyl
• CAS: 25941-10-0
• 化学式: C₆MoO₆
• 分子量: 269.936
• InChiKey: KMKBZNSIJQWHJA-VIURQLLDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 molybdenum hexacarbonyl 以 neat (no solvent) 为溶剂， 生成 Mo((13)CO)5(THF)
  参考文献：
  名称：

  Davis, Harry B.; Einstein, Frederick W. B.; Glavina, Paul G., Organometallics, 1989, vol. 8, # 4, p. 1030 - 1039

  摘要：

  DOI：
• 作为产物：
  描述：

  pentacarbonyl(tetrahydrofuran)molybdenum(0) 以 四氢呋喃 为溶剂， 生成 molybdenum hexacarbonyl
  参考文献：
  名称：

  Davis, Harry B.; Einstein, Frederick W. B.; Glavina, Paul G., Organometallics, 1989, vol. 8, # 4, p. 1030 - 1039

  摘要：

  DOI：

文献信息

• Reactions of Group 6 Fischer carbene complexes with alkynes: effect of the metal on the product distribution and the isolation of a nontautomerized cyclohexadienone complex
  作者：William D. Wulff、Brian M. Bax、Timothy A. Brandvold、Kin Shing Chan、Adam M. Gilbert、Richard P. Hsung、John Mitchell、Jon Clardy

  DOI：10.1021/om00013a021

  日期：1994.1

  The first comparative study on the effect of the nature of the metal on the reactions of unsaturated group 6 Fischer carbene complexes with alkynes is reported. The scope of the study includes both aryl- and alkenylcarbene complexes of chromium, molybdenum, and tungsten for both internal and terminal alkynes. Twenty-one different organic structural types have been isolated and characterized from these reactions, but in most instances phenols and indene (cyclopentadiene) products are the two most frequently observed. The general observation made is that phenol formation is favored over indene (cyclopentadiene) formation in the order chromium > tungsten > molybdenum. The effect of the concentration of the alkyne on the distribution between phenol and indene (cyclopentadiene) was also examined and was found to be most prevalent in the order molybdenum > chromium > tungsten. The bis(alkyne)(eta4-cyclohexadienone)molybdenum complex 107 has been isolated in which the final tautomerization to the phenol product has not occurred. This complex has been characterized by X-ray diffraction and provides support for the previous interpretations of the concentration effects for the reactions of chromium complexes. This complex is the first example of the long-proposed ultimate intermediate in these reactions. Crystal data for 107: space group P2(1)/c, Z = 4, a = 19.088(4) angstrom, b = 10.101(1) angstrom c = 14.578(3) angstrom, a = 90.0-degrees, beta = 109.917(13)-degrees, gamma = 90.0-degrees, R = 0.0598, and R(w) = 0.0788 for the 2405 reflections observed.
• Bricker, Jeffery C.; Payne, Martin W.; Shore, Sheldon G., Organometallics, 1987, vol. 6, # 12, p. 2545 - 2547
  作者：Bricker, Jeffery C.、Payne, Martin W.、Shore, Sheldon G.

  DOI：——

  日期：——
• Hsu, Gishun; Wilson, Scott R.; Shapley, John R., Inorganic Chemistry, 1996, vol. 35, # 4, p. 923 - 928
  作者：Hsu, Gishun、Wilson, Scott R.、Shapley, John R.

  DOI：——

  日期：——
• Metal alkoxides: models for metal oxides. 3. Further studies of the carbonylation of hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M) and characterization of M₂(O-i-Pr)₆(py)₂(μ-CO)(M:M) compounds
  作者：M. H. Chisholm、J. C. Huffman、J. Leonelli、I. P. Rothwell

  DOI：10.1021/ja00389a024

  日期：1982.12
• Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O
  作者：Donald J. Darensbourg、Nyal Walker、Marcetta Y. Darensbourg

  DOI：10.1021/ja00523a075

  日期：1980.1