tetrakis(((2,6-dimethylphenyl)-l4-azaneylidyne)methyl)rhodium(V) perchlorate | 61754-50-5

• 英文名称: tetrakis(((2,6-dimethylphenyl)-l4-azaneylidyne)methyl)rhodium(V) perchlorate
• CAS: 61754-50-5
• 化学式: C₃₆H₃₆N₄Rh*ClO₄
• 分子量: 727.065
• InChiKey: IHBAHRALAYUKJH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tetrakis(((2,6-dimethylphenyl)-l4-azaneylidyne)methyl)rhodium(V) perchlorate 、 lithium 7,7,8,8-tetracyanoquinodimethane 以 乙醇 、 乙腈 为溶剂， 生成 [Rh(2,6-Me2C6H3NC)4](+)(7,7,8,8-tetracyano-p-quinodimethane)2(.-)
  参考文献：
  名称：

  Synthesis and electrical resistivity of tetrakis(isocyanide)rhodium(I) cation-TCNQ radical anion salts

  摘要：

  DOI：

  10.1016/s0020-1693(00)90461-4

文献信息

• Preparation and properties of AzaTCNQ− anion salts and mixed AzaTCNQ−/ TCNQ⨪/TCNQ salts of some tetrakis(isocyanide)rhodium(I) cation, and x-ray crystal structure of the AzaTCNQ−-tetrakis(2,6-dimethylphenylisocyanide)rhodium(I)+ salt
  作者：Gen-Etsu Matsubayashi、Hirohisa Tanaka、Toshio Tanaka、Kazumi Nakatsu

  DOI：10.1016/s0020-1693(00)81916-7

  日期：1982.1

  H 3 , n = 0.2; R = C 6 H 5 and 2,4,6-Me 3 C 6 H 2 , n = 0.3), and [Rh(RNC) 4 ] + (ATCNQ − ) a9 (TCNQ ⨪ ) 0.1 (TCNQ) 0.8 (R = 2,6-Me 2 C 6 H 3 and 2,4,6-Me 3 C 6 H 2 ). Of these salts, [Rh(2,6-Me 2 C 6 H 3 NC) 4 ] + (ATCNQ − / TCNQ ⨪ and [Rh(2,6-Me 2 C 6 H 3 NC) 4 ] + (ATCNQ − )/ TCNQ ⨪ /TCNQ) exhibit electrical resistivities of ∼1 X 10 5 Ωcm as compacted samples at 25 °C and behave as typical semi-conductors

  摘要以下的ATCNQ-盐和ACTNQ-/ TCNQ⨪/ TCNQ混合盐（ATCNQ-= 4-二氰基亚甲基吡啶二氰基甲基化物，所谓的氮杂-四氰基喹二甲基阴离子； TCNQ = 7,7,8,8-四氰基-对-喹二甲基）制备了四（异氰化物）铑（I）阳离子；[Rh（RNC）4] + ATCNQ-（R = C 6 H 5，2,6-Me 2 C 6 H 3和2,4,6-Me 3 C 6 H 2），[Rh（RNC）4 ] +（ATCNQ −）n（TCNQ）））1-n（R = 2,6-Me 2 C 6 H 3，n = 0.2; R = C 6 H 5和2,4,6-Me 3 C 6 H 2，n = 0.3）和[Rh（RNC）4] +（ATCNQ-）a9（TCNQ⨪）0.1（TCNQ）0.8（R = 2,6-Me 2 C 6 H 3和2,4,6 -Me 3 C 6 H 2）。这些盐中，[Rh（2,6-Me 2 C
• Electron Transfer from Tetrakis(isocyanide)rhodium(I) Monomers, and the Oligomers to Iron(III) and Cobalt(III) Complexes. Enhancement of the Reactivity by the Oligomerization
  作者：Shunichi Fukuzumi、Nobuaki Nishizawa、Toshio Tanaka

  DOI：10.1246/bcsj.55.3482

  日期：1982.11

  Electron transfer reactions from tetrakis(isocyanide)rhodium(I) ([RhL4]+ to iron(III) complexes of the [Fe(N–N)3]3+ type (N–N=1,10-phenanthroline, 2,2′-bipyridine) proceed through precursor complexes formed between [RhL4]+ and [Fe(N–N)3]3+ with 1:1, 1:2, and 2:1 stoichiometry. A similar scheme is suggested for the reaction of bis(isocyanide)bis(triphenylphosphine)rhodium(I) with the same oxidants.

  2'-联吡啶），[RhL4+]n 的 logk1 值与 [RhL4+]n 的 HOMO 能量平行增加；单体