(PNP)Rh(η2-C2H4) | 881998-48-7

• 英文名称: (PNP)Rh(η2-C2H4)
• CAS: 881998-48-7
• 化学式: C₂₈H₄₄NP₂Rh
• 分子量: 559.517
• InChiKey: YYCUONIBLZYTFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 三乙基硼氢化钠 以 氘代苯 为溶剂， 生成 [RhClPh(bis(o-diisopropylphosphino-p-methylphenyl)amide)] 、 [(N(C6H3-4-Me-2-P(iPr)2)2)RhH2] 、 (PNP)Rh(η2-C2H4)
  参考文献：
  名称：

  Carbon−Halide Oxidative Addition and Carbon−Carbon Reductive Elimination at a (PNP)Rh Center

  摘要：

  An unsaturated (PNP)Rh fragment can be generated by means of C-C reductive elimination from (PNP)Rh(Me)(Ar) or (PNP)Rh(Ar)(Ar). This fragment undergoes carbon-halogen oxidative addition with aryl chlorides, bromides, and iodides at room temperature. The C-H oxidative addition products in reactions with haloarenes are not observed, and evidence is presented that carbon-halogen oxidative addition is thermodynamically preferred. C-C reductive elimination from (PNP)Rh(Me)(Ar) and (PNP)Rh(Ar)(Ar) proceeds near quantitatively as a clean, first-order reaction.

  DOI：

  10.1021/ja057948j