| 166603-73-2

• CAS: 166603-73-2
• 化学式: C₃₄H₂₈Cl₂FeN₂O₂P₂*Cl₄Fe
• 分子量: 882.968
• InChiKey: OGUARUKBEXQPPY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 silver nitrate 以 二氯甲烷 、 乙腈 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Oxygen transfer from iron nitrates in the presence of 2-(diphenylphosphine oxide)pyridine (OPPh2py). Molecular structure of Fe(NO3)2Cl(OPPh2py) · CH2Cl2

  摘要：

  [Fe(Cl)(4)][Fe(NO3)(2)(OPPh(2)py)(2)], 2, and [Fe(NO3)(2)(Cl)(OPPh(2)py)], 3, were obtained when [Fe(Cl)(4)][Fe(Cl)(2)(OPPh(2)py)(2)], 1, was allowed to react with respectively 2 and 4 eq. silver nitrate. Complexes 2 and 3 catalysed the autoxidation of cyclohexene. They transfer the oxygens of their nitrate groups to phosphines. Complex 3 has been characterized by single crystal X-ray diffraction. The bite of the OPPh(2)py ligand repels the presence of the chlorine atom in the Fe(NO3)(2) plane of 3 which influences the geometric features of the nitrate groups, their oxygen transfer ability.

  DOI：

  10.1016/0277-5387(94)00372-l
• 作为产物：
  描述：

  三氯化铁 、 2-(diphenylphosphoryl)pyridine 以 二氯甲烷 、 乙腈 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Oxygen transfer from iron nitrates in the presence of 2-(diphenylphosphine oxide)pyridine (OPPh2py). Molecular structure of Fe(NO3)2Cl(OPPh2py) · CH2Cl2

  摘要：

  [Fe(Cl)(4)][Fe(NO3)(2)(OPPh(2)py)(2)], 2, and [Fe(NO3)(2)(Cl)(OPPh(2)py)], 3, were obtained when [Fe(Cl)(4)][Fe(Cl)(2)(OPPh(2)py)(2)], 1, was allowed to react with respectively 2 and 4 eq. silver nitrate. Complexes 2 and 3 catalysed the autoxidation of cyclohexene. They transfer the oxygens of their nitrate groups to phosphines. Complex 3 has been characterized by single crystal X-ray diffraction. The bite of the OPPh(2)py ligand repels the presence of the chlorine atom in the Fe(NO3)(2) plane of 3 which influences the geometric features of the nitrate groups, their oxygen transfer ability.

  DOI：

  10.1016/0277-5387(94)00372-l