[PtPdCl3(SeCH2CH2NMe2)(PEt3)2] | 1105066-79-2

• 英文名称: [PtPdCl3(SeCH2CH2NMe2)(PEt3)2]
• CAS: 1105066-79-2
• 化学式: C₁₆H₄₀Cl₃NP₂PdPtSe
• 分子量: 795.267
• InChiKey: HRIPZEBNLBOCGA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PtPdCl3(SeCH2CH2NMe2)(PEt3)2] 以 not given 为溶剂， 生成 顺-二氯双(三乙基膦)铂(II) 、 [PdCl(SeCH2CH2NMe2)]3
  参考文献：
  名称：

  Homo- and hetero-, bi- and tri-nuclear palladium(II) and platinum(II) complexes containing single bridging chalcogenolate of a metallo-ligand, [MCl(ECH2CH2NMe2)(PR3)] (M=Pt, Pd; E=Se, Te)

  摘要：

  Bi- and tri-nuclear palladium/platinum complexes of the types [MCl(ECH2CH2NMe2)(PR3)M'Cl-2(PR3)] (M, M'= Pd or Pt) and [{PtCl(SeCH2CH2NMe2)(PR3)}(2)M' Cl-2] (M' = Pd or Pt; PR3 = PEt3 or PPr3n) have been prepared. All complexes were characterized 3 by elemental analysis, NMR (H-1, (31)p, Se-77, Te-125, Pt-195) data. The structures of [PdCl(SeCH2CH2NMe2)(PPh3)PtCl2(PPh3)] and [{PtCl(SeCH2CH2NMe2)(PEt3)}(2)PtCl2] have been established by single crystal X-ray diffraction analysis. In the latter complex, three square planar platinum atoms are held together by the single bridging selenolate group in an almost linear chain arrangement. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.08.014
• 作为产物：
  描述：

  {Pt2Cl2(μ-Cl)2(PMePh2)2} 、 PdCl(SeCH2CH2NMe2)(PEt3) 以 丙酮 为溶剂， 以52%的产率得到[PtPdCl3(SeCH2CH2NMe2)(PEt3)2]
  参考文献：
  名称：

  Homo- and hetero-, bi- and tri-nuclear palladium(II) and platinum(II) complexes containing single bridging chalcogenolate of a metallo-ligand, [MCl(ECH2CH2NMe2)(PR3)] (M=Pt, Pd; E=Se, Te)

  摘要：

  Bi- and tri-nuclear palladium/platinum complexes of the types [MCl(ECH2CH2NMe2)(PR3)M'Cl-2(PR3)] (M, M'= Pd or Pt) and [{PtCl(SeCH2CH2NMe2)(PR3)}(2)M' Cl-2] (M' = Pd or Pt; PR3 = PEt3 or PPr3n) have been prepared. All complexes were characterized 3 by elemental analysis, NMR (H-1, (31)p, Se-77, Te-125, Pt-195) data. The structures of [PdCl(SeCH2CH2NMe2)(PPh3)PtCl2(PPh3)] and [{PtCl(SeCH2CH2NMe2)(PEt3)}(2)PtCl2] have been established by single crystal X-ray diffraction analysis. In the latter complex, three square planar platinum atoms are held together by the single bridging selenolate group in an almost linear chain arrangement. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.08.014