bis[2-[[(2-tosylaminophenyl)methylidene]amino]pyridin-3-olato]dicopper(II) | 1170726-80-3

• 英文名称: bis[2-[[(2-tosylaminophenyl)methylidene]amino]pyridin-3-olato]dicopper(II)
• CAS: 1170726-80-3
• 化学式: C₃₈H₃₀Cu₂N₆O₆S₂
• 分子量: 857.917
• InChiKey: XAGQTWOAUVAEER-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-氨基-3-羟基吡啶 、 N-(2-甲酰基苯基)-4-甲基苯磺酰胺 、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 以70%的产率得到bis[2-[[(2-tosylaminophenyl)methylidene]amino]pyridin-3-olato]dicopper(II)
  参考文献：
  名称：

  Molecular design of new magnetically active copper complexes with heteroaromatic schiff bases and azo compounds

  摘要：

  Copper chelates with tridentate ligands containing pyridine or pyrazole ring at the azomethine or azo fragment were synthesized by chemical electrochemical methods, and their structure was characterized by the EXAFS spectra. Thermal rnagnetochemical analysis of the complexes revealed anti ferromagnetic exchange interaction in all complexes. The exchange interaction parameter of the complex containing an N-tosylamino C7 C oroup in the ortho position with respect to the azomethine aroup is much lesser than that of the corresponding complex having an oxygen atom in the same position. The copper chelate derived from azopyrazole ligand C! shows low-temperature ferromagnetic phase transition.

  DOI：

  10.1134/s1070363208060224