3-[chloro{5,10,15-tris(4-methylphenyl)porphyrinato}indium(III)-20-yl]-9-hexyl-carbazole | 1340541-08-3

• 英文名称: 3-[chloro{5,10,15-tris(4-methylphenyl)porphyrinato}indium(III)-20-yl]-9-hexyl-carbazole
• CAS: 1340541-08-3
• 化学式: C₅₉H₄₉ClInN₅
• 分子量: 978.345
• InChiKey: PMYVFEKMQDSRJP-MIECGNOMSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-(5,10,15-tris(4-methylphenyl)porphyrin-20-yl)-9-hexyl-carbazole 在 indium(III) chloride 、 sodium acetate 、 溶剂黄146 作用下， 反应 18.0h， 以59%的产率得到3-[chloro{5,10,15-tris(4-methylphenyl)porphyrinato}indium(III)-20-yl]-9-hexyl-carbazole
  参考文献：
  名称：

  Carbazole-linked porphyrin dimers for organic light emitting diodes: synthesis and initial photophysical studies

  摘要：

  Carbazole linked porphyrin dimers were synthesized in good yields via stepwise Suzuki coupling reactions using bromoporphyrins and borylated carbazoles as the precursors, the latter of which were synthesized via known procedures from biphenyl derivatives. For comparative purposes porphyrin-carbazole monomers were synthesized. Single layer organic light emitting diodes (OLEDs) were created to demonstrate the optical properties of these materials. Light emission from these carbazole substituted porphyrins showed better results compared to previously examined bromo substituted porphyrins with better electroluminescence and lower turn-on voltages. Dimers exhibited turn-on voltages of 3 V compared to 6 V for monomeric porphyrin-carbazoles. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.08.096