trans-[W(dinitrogen)(1,1'-bis(diethylphosphino)ruthenocene)(PPh2Me)2] | 1182298-45-8

• 英文名称: trans-[W(dinitrogen)(1,1'-bis(diethylphosphino)ruthenocene)(PPh2Me)2]
• CAS: 1182298-45-8
• 化学式: C₄₄H₅₄N₄P₄RuW
• 分子量: 1047.75
• InChiKey: HYZMCKFNMVNJTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  硫酸 、 trans-[W(dinitrogen)(1,1'-bis(diethylphosphino)ruthenocene)(PPh2Me)2] 以 甲醇 为溶剂， 生成 Ammonium
  参考文献：
  名称：

  Synthesis and Protonolysis of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ruthenocenyldiphosphines

  摘要：

  Tungsten- and molybdenum-dinitrogen complexes bearing 1, 1'-bis(diethylphosphino)ruthenocene (depr) or 1,1'-bis(dimethylphosphino)ruthenocene (dmpr) have been prepared and characterized spectroscopically. Reactions of tungsten- and molybdenum- dinitrogen complexes bearing ruthenocenyldiphosphines with an excess amount of sulfuric acid in methanol at room temperature give ammonia in good yields.

  DOI：

  10.1021/om900298g
• 作为产物：
  描述：

  trans-[W(dinitrogen)(PMePh2)4]*1.5THF 、 1,1-bis(diethylphosphino)ruthenocene 以 四氢呋喃 为溶剂， 以29%的产率得到trans-[W(dinitrogen)(1,1'-bis(diethylphosphino)ruthenocene)(PPh2Me)2]
  参考文献：
  名称：

  Synthesis and Protonolysis of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ruthenocenyldiphosphines

  摘要：

  Tungsten- and molybdenum-dinitrogen complexes bearing 1, 1'-bis(diethylphosphino)ruthenocene (depr) or 1,1'-bis(dimethylphosphino)ruthenocene (dmpr) have been prepared and characterized spectroscopically. Reactions of tungsten- and molybdenum- dinitrogen complexes bearing ruthenocenyldiphosphines with an excess amount of sulfuric acid in methanol at room temperature give ammonia in good yields.

  DOI：

  10.1021/om900298g