| 75200-30-5

• CAS: 75200-30-5
• 化学式: C₁₂H₂₆Br₂N₂Pt
• 分子量: 553.24
• InChiKey: ZJSHVOVQMQTJIX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以54%的产率得到
  参考文献：
  名称：

  Conformational isomerism of trans-[Pt(NH2C6H11)2I2] and the classical Wernerian chemistry of [Pt(NH2C6H11)4]X2 (X=Cl, Br, I)

  摘要：

  X-ray crystallographic analysis of the compound trans-[Pt(NH2C6H11)(2)I-2] revealed the presence of two distinct conformers within one crystal lattice. This compound was studied by variable temperature NMR spectroscopy to investigate the dynamic interconversion between these isomers. The results of this investigation were interpreted using physical (CPK) and computational (molecular mechanics and density functional theory) models. The conversion of the salts [Pt(NH2C6H11)(4)]X-2 into trans-[Pt(NH2C6H11)(2)X-2] (X = Cl, Br, I) was also studied and is discussed here with an emphasis on parallels to the work of Alfred Werner. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.010