| 1110784-76-3

• CAS: 1110784-76-3
• 化学式: C₂₀H₁₃MnO₄S
• 分子量: 404.325
• InChiKey: PXRHKICOZKBEAM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-噻吩甲酰氯 、 (η5-6-exo-phenylcyclohexadienyl)manganesetricarbonyl 在 iron(III)-acetylacetonate n-BuLi 、 TMEDA 、 MnCl₄Li₂ 作用下， 以 四氢呋喃 为溶剂， 以24%的产率得到
  参考文献：
  名称：

  A Simple Route to Keto-Substituted (η⁵-Cyclohexadienyl)Mn(CO)₃ Complexes Using Organomanganese Transmetalation: Structural and Theoretical Characterizations

  摘要：

  Efficient synthesis of keto-substituted (eta(5)-cyclohexadienyl)Mn(CO)(3) complexes is achieved by, organomanganese transmetalation catalyzed by Fe(acac)(3). Density junctional theory (DFT) calculations highlight the influence of the keto group position on the strength of conjugation between the RCO function and the cyclohexadienyl ring and shed light on the regioselectivity of nucleophilic attacks on such complexes.

  DOI：

  10.1021/om800863t