| 86880-31-1

• CAS: 86880-31-1
• 化学式: C₃H₂FeO₃
• 分子量: 141.894
• InChiKey: VWWURSDSLSEJLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氢气 以 gas 为溶剂， 生成
  参考文献：
  名称：

  A study of the kinetics of reaction of iron tricarbonyl and Fe(CO)3(L) with hydrogen and ethene for L = hydrogen and ethene by transient Infrared spectroscopy: reactions relevant to olefin hydrogenation kinetics

  摘要：

  The reactions of Fe(CO)3 with ethylene and H-2 have been studied and rate constants for the formation of the H2Fe(CO)3 and Fe(CO)3(ethylene) complexes have been obtained. Further reactions of these unsaturated products with ethylene and H-2 respectively have been shown to lead to formation of the H2Fe(CO)3(ethylene) complex which is a crucial intermediate in the proposed mechanism for Fe(CO)3-induced hydrogenation of ethylene. The rate constants for formation of this complex from both precursors have been obtained and are reported along with the other rate constants determined in this study. Interestingly, though ethane is produced on a long time scale under the experimental conditions, H2Fe(CO)3(ethylene) is stable at room temperature in the approximately 100-mu-s observation time of these experiments. Significant differences have been observed for the rate constants of formation of the various complexes that were studied. These variations are discussed with respect to spin allowed versus disallowed reactions and the nature of the reacting ligand.

  DOI：

  10.1021/j100160a020
• 作为产物：
  描述：

  以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  铁催化烷氧基化、脱氢聚合和串联氢化硅烷化烷氧基化

  摘要：

  Si−O−C 键的构建一直是贵重、稀有、后过渡金属催化剂的垄断。本文报道了一种分子定义的铁络合物，其催化烷氧基化、脱氢聚合和串联氢化硅烷化-烷氧基化，仅产生H 2作为副产物。该铁催化剂能耐受一系列醇、硅烷，并在温和条件下以优异的产率产生 Si−O 偶联产物。

  DOI：

  10.1002/chem.202301375

文献信息

• Hydrosilylation cross-linking of silicon fluids by a novel class of iron(0) catalysts
  作者：Bogdan Marciniec、Agnieszka Kownacka、Ireneusz Kownacki、Richard Taylor

  DOI：10.1016/j.apcata.2014.08.037

  日期：2014.9

  L = diene, triene, tetraene, polyvinyl silicon derivatives) were examined as novel catalysts in the molecular model of cross-linking process as well as various polymeric silicone systems. In the model reactions between vinylheptamethyltrisiloxane and heptamethyltrisiloxane, these complexes proved to be efficient catalysts of dehydrogenative silylation, while in polymeric systems, made of silicone fluids

  通式[Fe（CO）3（L）]，[Fe（CO）3 } 2的铁（0）羰基配合物在交联过程以及各种聚合物有机硅体系的分子模型中，研究了由多乙烯基硅配体（其中L =二烯，三烯，四烯，聚乙烯硅衍生物）稳定的L]作为新型催化剂。在乙烯基七甲基三硅氧烷和七甲基三硅氧烷之间的模型反应中，这些络合物被证明是脱氢甲硅烷基化的有效催化剂，而在由硅油（如聚（乙烯基）硅氧烷和聚氢硅氧烷）制成的聚合物体系中，氢化硅烷化在高温下得到了有效催化。事实证明，添加到这些硅流体混合物中的复合物在延长的存储时间后仍具有活性，即使暴露在空气和湿气中也是如此。[Fe（CO）3 （H 2C CHSiMe 2）2 O}]与分子底物的结合，以及在这些络合物存在下在液相中进行的交联催化试验，提出了新的羰基铁催化氢化硅烷化与脱氢甲硅烷基化的机理方案其中[Fe（CO）3 ]部分被多乙烯基硅衍生物稳定的催化剂。
• Iron Catalyzed Hydroformylation of Alkenes under Mild Conditions: Evidence of an Fe(II) Catalyzed Process
  作者：Swechchha Pandey、K. Vipin Raj、Dinesh R. Shinde、Kumar Vanka、Varchaswal Kashyap、Sreekumar Kurungot、C. P. Vinod、Samir H. Chikkali

  DOI：10.1021/jacs.8b01286

  日期：2018.3.28

  4-chloro styrene (S18), 4-vinylbenzonitrile (S19), 4-vinylbenzoic acid (S20), and allyl benzene (S21) to corresponding aldehydes in good to excellent yields. Both electron donating and electron withdrawing substituents could be tolerated and excellent conversions were obtained for S11-S20. Remarkably, the addition of 1 mol % acetic acid promotes the reaction to completion within 16-24 h. Detailed mechanistic

  地球上储量丰富的第一排过渡金属为稀有和贵金属提供了一种廉价且可持续的替代品。然而，在催化中使用第一行金属需要苛刻的反应条件，活性有限，并且不能耐受官能团。这里报道的是一种在温和条件下高效铁催化的烯烃加氢甲酰化反应。该协议在低于 100 °C 的 10-30 bar 合成气压力下运行，利用现成的配体，并适用于一系列烯烃。因此，铁前体 [HFe(CO)4]-[Ph3PNPPh3]+ (1) 在三苯基膦存在下催化 1-己烯 (S2)、1-辛烯 (S1)、1-癸烯 (S3) 的加氢甲酰化, 1-十二烯 (S4), 1-十八烯 (S5), 三甲氧基(乙烯基)硅烷 (S6), 三甲基(乙烯基)硅烷 (S7), 腰果酚 (S8), 2,3-二氢呋喃 (S9), 烯丙基丙二酸(S10), 苯乙烯 (S11), 4-甲基苯乙烯 (S12), 4-异丁烯-苯乙烯 (S13), 4-丁丁-苯乙烯 (S14), 4-甲氧基苯乙烯