1,1,4,4-tetramethyl-1,4-disilabutylene-titanocene | 130904-27-7

• 英文名称: 1,1,4,4-tetramethyl-1,4-disilabutylene-titanocene
• CAS: 130904-27-7
• 化学式: C₁₆H₂₄Cl₂Si₂Ti
• 分子量: 391.324
• InChiKey: HTNUWXNPBTULMQ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  四氯化钛 、 1,4-dicyclopentadienyl-1,1,4,4-tetramethyl-1,4-disilabutylene, dilithium salt 以 四氢呋喃 、 甲苯 为溶剂， 以23%的产率得到1,1,4,4-tetramethyl-1,4-disilabutylene-titanocene
  参考文献：
  名称：

  4-ansa-茂金属络合物：1,1,4,4-四甲基-1,4-二硅丁烯桥连的钛茂，锆茂和ha茂衍生物的合成

  摘要：

  Titanocene, zirconocene, and hafnocene derivatives with an interannular 1,1,4,4-tetramethyl-1,4-disilabutylene bridge were synthesized by the reaction of the dillithium derivative of 1,4-dicyclopentadienyl-1,1,4,4-tetramethyl-1, 4-disilabutane with titanium, zirconium, and hafnium tetrachlorides in THF. The identities of all new compounds have been documented by analytical as well as by spectroscopic (IR, MS, H-1 and C-13 NMR) data.

  DOI：

  10.1021/om00047a071