[Fe2S2(CO)4(PPh3)2] | 757953-40-5

• 英文名称: [Fe2S2(CO)4(PPh3)2]
• CAS: 757953-40-5
• 化学式: C₄₀H₃₀Fe₂O₄P₂S₂
• 分子量: 812.449
• InChiKey: FPADXRWIIUAZRS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 三苯基膦 在 LiEt₃BH 、 CuCl 、 Et₄NCl 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 以21.9%的产率得到[Fe2S2(CO)4(PPh3)2]
  参考文献：
  名称：

  Synthesis, structure and formation pathways of new Fe–S complexes containing [Fe2S2]-units in different valences, [Fe2S2(CO)4(PPh3)2], [Fe3S2(CO)6(PPh3)3] and [Fe4S2(CO)10]2− and the origin of the [Fe2S2]-unit in metal–[Fe2S2(CO)6] complexes

  摘要：

  Novel Fe-S cluster complexes, [Fe2S2(CO)(4)(PPh3)(2)] (1), [Fe3S2(CO)(6)(PPh3)(3)] (2) and [Ph4P](2)[Fe4S2(CO)(10)] (3) have been synthesized by the reaction of LiEt3BH with [Fe2S2(CO)(6)] in the presence of CuCl-PPh3, AgNO3-PPh3 and CuClO3-MeCN, respectively. Structure determination indicated that 1, 2 and 3, respectively, possessed [Fe2S2](0) core with [Fe2S2](0)-unit, [Fe3S2](0) with [Fe2S2](2-) and [Fe4S2](2-) core with [Fe2S2](4-) unit, which implied that [Fe2S2(CO)(6)](2-), as a starting material, underwent a disproportionation in the synthetic reaction. Investigating the structure and synthetic reaction, an origin of the different valence[Fe2S2]-units and formation pathways of those clusters via disproportionation of the [Fe2S2(CO)(6)](2-) following by 'Unit Construction' were proposed and discussed. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.036