ferrocene-formanilide-anthraquinone triad | 655249-75-5

• 英文名称: ferrocene-formanilide-anthraquinone triad
• CAS: 655249-75-5
• 化学式: C₃₁H₂₁FeNO₃
• 分子量: 511.36
• InChiKey: FDGZQXNZFRNWII-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  ferrocene-formanilide-anthraquinone triad 、 yttrium(III) trifluoromethanesulfonate 以 苯甲腈 为溶剂， 生成
  参考文献：
  名称：

  A Dramatic Elongation of the Lifetime of Charge-Separated State by Complexation with Yttrium Triflate in Ferrocene−Anthraquinone Linked Dyad

  摘要：

  Seven million times elongation of the lifetime of charge-separated state is attained in the presence of yttrium triflate [Y(OTf)3] in the photoinduced electron-transfer reaction of a ferrocene-anthraquinone dyad (Fc-AQ) with a rigid amide spacer in benzonitrile at 298 K as compared with the lifetime in its absence. Such remarkable elongation of the CS lifetime in the presence of Y(OTf)3 results from the strong binding of Y(OTf)3 with the AQ*- moiety of Fc+-AQ*-.

  DOI：

  10.1021/ja037025t