| 69793-93-7

• CAS: 69793-93-7
• 化学式: ClH₁₀MnO₅
• 分子量: 180.467
• InChiKey: XUNQVAVFQOCLKW-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  dichlorine radical anion 、 manganese(II) perchlorate hexahydrate 以 水 为溶剂， 生成
  参考文献：
  名称：

  Magnetic field effects in rates of reactions between radicals and transition metal coordination complexes of cobalt(II) and manganese(II): probes for spin polarization

  摘要：

  The effect of magnetic fields on the rates of reactions of Cl-2-, Br-2-, and CO3H with Co(II) and Mn(II) complexes was investigated as a function of the field intensity between 0 and 7 T. The Delta g mechanism and suppression of HFC-induced transitions in radical-ion pairs account for effects observed at less than 0.3 T on reactions with high-spin Co(II) complexes. In the reaction between Co(Me(6)-[14]dieneN(4))(2+) and Cl-2-, MFE on the rate are mostly related to the suppression of HFC-induced transitions in the radical-ion pairs. In a number of these processes the reaction rate constant increases with field and the sense of MFE in reactions of the CO3H radical appears inverted with respect to reactions of Cl-2- and Br-2-. A mechanism that accounts for such differences is discussed.

  DOI：

  10.1021/j100148a014