[(CH3C5H4)2Y(η2-S2CNPh2)]2*CH3C6H5 | 441052-48-8

• 英文名称: [(CH3C5H4)2Y(η2-S2CNPh2)]2*CH3C6H5
• CAS: 441052-48-8
• 化学式: C₇H₈*C₅₀H₄₈N₂S₄Y₂
• 分子量: 1075.16
• InChiKey: LDJUZFXTXUBIBW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二硫化碳 、 (MeC5H4)2YNPh2(tetrahydrofuran) 、 甲苯 以 二硫化碳 、 甲苯 为溶剂， 以88.5%的产率得到[(CH3C5H4)2Y(η2-S2CNPh2)]2*CH3C6H5
  参考文献：
  名称：

  The Reactivity of (CH₃C₅H₄)₂LnNPh₂(THF) (Ln = Y, Yb) with CS₂ and PhNCS:  Synthesis and Crystal Structures

  摘要：

  The insertion reactions Of CS2 and phenyl isothiocyanate into the Ln-N bond of lanthanocene diphenylamide were first studied, and the insertion products, viz., [(CH3C5H4)(2) Y(eta(2) - S2CNPh2)](2) .CH3C6H5 (1), [(CH3C5H4)(2)Yb(eta(2) -S2CNPh2)] (2), and {(CH3C5H4)(2)Y-[eta(2)-SC(NPh2)NPh]} (3), were obtained. All the new complexes were characterized by single-crystal X-ray diffraction. Both I and 3 have dimeric structure, which have an interlinked tricycle formed via two bridged S atoms, while 2 exists as a monomer.

  DOI：

  10.1021/om0109509