[PdCl2(Pd[2-ClC6H3C(Me)=NN=C(S)NHEt](Ph2PCH2PPh2)-P,S)] | 640285-65-0

• 英文名称: [PdCl2(Pd[2-ClC6H3C(Me)=NN=C(S)NHEt](Ph2PCH2PPh2)-P,S)]
• CAS: 640285-65-0
• 化学式: C₃₆H₃₄Cl₃N₃P₂Pd₂S
• 分子量: 921.899
• InChiKey: DYYYLSKHCAUZSH-RJVKBKGPSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 [Pd(2-ClC6H3C(Me)NNC(S)NHEt)(Ph2PCH2PPh2-P)] 以 丙酮 为溶剂， 以81%的产率得到[PdCl2(Pd[2-ClC6H3C(Me)=NN=C(S)NHEt](Ph2PCH2PPh2)-P,S)]
  参考文献：
  名称：

  Palladium(II) Cyclometalated Thiosemicarbazone Compounds:  A New Class of Bidentate P,S Metallo Ligands

  摘要：

  Reaction of the tetranuclear compounds 1-4 with bis(diphenylphosphino)methane gave the mononuclear complexes 5-8, with the diphosphine ligand binding in a monodentate fashion. Compounds 5-8 are capable of bonding systematically to a second palladium atom through the noncoordinated phosphorus atom and the sulfur atom of the thiosemicarbazone moiety to give the dinuclear compounds 9-12, thus behaving as new bidentate PS-metallo ligands. All of the compounds have been characterized by IR and NMR spectroscopy, and the molecular structure of 9 has been determined by X-ray crystallography.

  DOI：

  10.1021/om034154+