[Rh(NBD)(κ(3)N,N,H-(HB(azaindolyl)3))] | 1187062-33-4

• 英文名称: [Rh(NBD)(κ(3)N,N,H-(HB(azaindolyl)3))]
• 英文别名: [Rh(2,5-norbornadiene)(κ(3)N,N,H-(HB(azaindolyl)3))]
• CAS: 1187062-33-4
• 化学式: C₂₈H₂₄BN₆Rh
• 分子量: 558.255
• InChiKey: OOBPPKTYJKYYHY-IDMSHCHPSA-N

反应信息

• 作为反应物：
  描述：

  [Rh(NBD)(κ(3)N,N,H-(HB(azaindolyl)3))] 以 not given 为溶剂， 生成 [Rh{κ4-NNBN-B-(azaindolyl)3}(nortricyclyl)]
  参考文献：
  名称：

  Further Exploring the “Sting of the Scorpion”: Hydride Migration and Subsequent Rearrangement of Norbornadiene to Nortricyclyl on Rhodium(I)

  摘要：

  A new boron-based flexible scorpionate ligand based upon 7-azaindole, Li[Ph(H)B(azaindolyl)(2)] (Li[(Ph)Bai]), has been prepared. This ligand, together with the previously reported ligand K[HB(azaindolyl)(3)] (K[Tai]), have been used to prepare a range of monovalent group 9 transition-metal complexes. The complexes [M(COD){kappa N-3,N,H-Ph(H)B(azaindolyl)(2)}] (where M = rhodium, iridium and COD = 1,5-cyclooctadiene) and [Rh(NBD){kappa N-3,N,H-HB(R)(azaindolyl)(2)}] (where NBD = 2,5-norbornadiene and R = Ph, azaindolyl) have been prepared. Structural characterization of [M(COD){kappa(3) NNH-Ph(H)B(azaindolyl)(2)}] (where M = rhodium, iridium) and [Rh(NBD){kappa N-3, N,H-HB(azaindolyl)(3)}] reveal strong interactions of the B-H functional group with the metal centers, particularly in the case of [Ir(COD){kappa N-3,NH-Ph(H)B(azaindolyl)(2)}]. The complex [Rh(NBD){kappa(3) NN,H-HB(azaindolyl)(3)}] undergoes a further reaction, resulting from hydride migration from boron to the norbornadiene group. Subsequent rearrangement results in the formation of the rhodium-nortricyclyl complex [Rh(norticyclyl){kappa N-4,N,B,N-B(azaindolyl)(3)}], providing the first nitrogen-based metallaboratrane complex to contain the tetradentate (kappa N-4,N,B,N) coordination mode.

  DOI：

  10.1021/om900499v
• 作为产物：
  描述：

  potassium tetrakis(7-azaindolyl)borate 、 di-μ-chlorobis(norbornadiene)dirhodium(I) 以 四氢呋喃 为溶剂， 以73%的产率得到[Rh(nortricyclyl)(κ(4)N,N,B,N-B(azaindolyl)3)]
  参考文献：
  名称：

  Further Exploring the “Sting of the Scorpion”: Hydride Migration and Subsequent Rearrangement of Norbornadiene to Nortricyclyl on Rhodium(I)

  摘要：

  A new boron-based flexible scorpionate ligand based upon 7-azaindole, Li[Ph(H)B(azaindolyl)(2)] (Li[(Ph)Bai]), has been prepared. This ligand, together with the previously reported ligand K[HB(azaindolyl)(3)] (K[Tai]), have been used to prepare a range of monovalent group 9 transition-metal complexes. The complexes [M(COD){kappa N-3,N,H-Ph(H)B(azaindolyl)(2)}] (where M = rhodium, iridium and COD = 1,5-cyclooctadiene) and [Rh(NBD){kappa N-3,N,H-HB(R)(azaindolyl)(2)}] (where NBD = 2,5-norbornadiene and R = Ph, azaindolyl) have been prepared. Structural characterization of [M(COD){kappa(3) NNH-Ph(H)B(azaindolyl)(2)}] (where M = rhodium, iridium) and [Rh(NBD){kappa N-3, N,H-HB(azaindolyl)(3)}] reveal strong interactions of the B-H functional group with the metal centers, particularly in the case of [Ir(COD){kappa N-3,NH-Ph(H)B(azaindolyl)(2)}]. The complex [Rh(NBD){kappa(3) NN,H-HB(azaindolyl)(3)}] undergoes a further reaction, resulting from hydride migration from boron to the norbornadiene group. Subsequent rearrangement results in the formation of the rhodium-nortricyclyl complex [Rh(norticyclyl){kappa N-4,N,B,N-B(azaindolyl)(3)}], providing the first nitrogen-based metallaboratrane complex to contain the tetradentate (kappa N-4,N,B,N) coordination mode.

  DOI：

  10.1021/om900499v