[Pt(dichloroamine(-1H))2(pyridine)2Cl2] | 868747-06-2

• 英文名称: [Pt(dichloroamine(-1H))2(pyridine)2Cl2]
• 英文别名: cis(*)-[Pt(NCl2)(*)2Py(*)2Cl2(*)]；trans(*)-[Pt(NCl2)2(pyridine)2Cl2(*)]
• CAS: 868747-06-2
• 化学式: C₁₀H₁₀Cl₆N₄Pt
• 分子量: 594.014
• InChiKey: KVKQTRYLYJDXDR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 [Pt(dichloroamine(-1H))2(pyridine)2Cl2] 以 盐酸 为溶剂， 以85%的产率得到{Pt()}Cl2*4H2O
  参考文献：
  名称：

  Destruction of the propylenediamine ring upon the chlorination of the platinum(IV) tetramine complex [PtpnPy2Cl2]Cl2

  摘要：

  The chlorination of an aqueous solution of [PtpnPy(2)Cl(2)]Cl(2) affords the platinum(IV) dichloroamine complex [PtPy(2)(NCl(2))(2)Cl(2)] (I), as the major reaction product formed due to the complete destruction of the five-membered chelate ring. Complex I is obtained in the pure state from acetonitrile. In addition, the [PtPy(NH(2)-CH(CH(3))-CH(CH(3))-NH(2))Cl(3)]Cl center dot 1/2H(2)O complex (II) is isolated from the mother liquor upon chlorination. Complex I reacts rapidly with concentrated HCl to form the tetramine complex [PtPy(2)(NH(3))(2)Cl(2)](CF(3)SO(3))(2) center dot 1/2H(2)O (III). The X-ray diffraction study is carried out for complexes I, II, and III. Complex I crystallizes in the monoclinic crystal system: space group C2/c, a = 7.4529(4), b = 15.2143(9), c = 14.9965(8) angstrom, beta = 99.866(1)degrees, V = 1675.3(2) angstrom(3), Z = 4; R(hkl) = 0.040. The crystals of complex II are triclinic: space group P (1) over bar, a = 8.163(2), b = 8.656(2), c = 10.638(2) angstrom, alpha = 78.30(3)degrees, beta = 83.95(3)degrees, gamma = 84.68(3)degrees, V = 730.0(3) angstrom(3), Z = 2; R(hkl) = 0.026. The crystals of complex III are monoclinic: space group C2/c, a = 11.946(2), b = 19.624(4), c = 10.034(2) angstrom, beta = 95.96(3)degrees, V = 2339.5(8) angstrom(3), Z = 4; R(hkl) = 0.043. The IR spectra of all the compounds synthesized are studied.

  DOI：

  10.1134/s0036023608120073
• 作为产物：
  描述：

  trans-[Pt(trimethylenediamine)(pyridine)2Cl2*]Cl2 、 氯 以 水 为溶剂， 以75%的产率得到[Pt(dichloroamine(-1H))2(pyridine)2Cl2]
  参考文献：
  名称：

  Fedotova; Kravchenko; Sakharov, Russian Journal of Inorganic Chemistry, 2005, vol. 50, # 4, p. 527 - 533

  摘要：

  DOI：