[Fe(NO3)2Cl(2-(diphenylphosphino)pyridine)] | 165815-67-8

• 英文名称: [Fe(NO3)2Cl(2-(diphenylphosphino)pyridine)]
• CAS: 165815-67-8
• 化学式: C₁₇H₁₄ClFeN₃O₇P
• 分子量: 494.588
• InChiKey: KBRIYMNKJYQOLJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Fe(NO)2Cl(2-(diphenylphosphino)pyridine)] 、 氧气 以 甲苯 为溶剂， 以72%的产率得到[Fe(NO3)2Cl(2-(diphenylphosphino)pyridine)]
  参考文献：
  名称：

  Reactivity of 2-(diphenylphosphino)pyridine and 2-(diphenylphosphine oxide)pyridine towards iron nitrosyl complexes and its relevance to oxygen activation

  摘要：

  The nitrosyl dimer [Fe(NO)(2)Cl](2) (1) in the presence of 2-(diphenylphosphino)pyridine (PN) yields the [Fe(NO)(2)Cl(PPh(2)py)] (2) complex in which the PN ligand is bound to iron monodentate through its phosphorus atom. 2 is unstable and rapidly evolves to [Fe(NO)Cl(OPPh(2)py)] (3): coordination of the nitrogen atom of the PN ligand results in NO substitution and oxygenation of the PN ligand to the bidentate 2-(diphenylphosphine oxide)pyridine (OPN). The same compound 3 is obtained when 1 is allowed to react with the OPN ligand. Oxidation by oxygen (1 atm) of the Fe-NO moiety in 2, 3 or 1 in the presence of PN or OPN, results in the formation of the nitrate complex Fe(NO3)(2)Cl(OPN) (4).

  DOI：

  10.1016/0020-1693(95)04460-q

文献信息

• Oxygen transfer from iron nitrates in the presence of 2-(diphenylphosphine oxide)pyridine (OPPh2py). Molecular structure of Fe(NO3)2Cl(OPPh2py) · CH2Cl2
  作者：Jean-Pierre Damiano、Viateur Munyejabo、Michele Postel

  DOI：10.1016/0277-5387(94)00372-l

  日期：1995.5

  [Fe(Cl)(4)][Fe(NO3)(2)(OPPh(2)py)(2)], 2, and [Fe(NO3)(2)(Cl)(OPPh(2)py)], 3, were obtained when [Fe(Cl)(4)][Fe(Cl)(2)(OPPh(2)py)(2)], 1, was allowed to react with respectively 2 and 4 eq. silver nitrate. Complexes 2 and 3 catalysed the autoxidation of cyclohexene. They transfer the oxygens of their nitrate groups to phosphines. Complex 3 has been characterized by single crystal X-ray diffraction. The bite of the OPPh(2)py ligand repels the presence of the chlorine atom in the Fe(NO3)(2) plane of 3 which influences the geometric features of the nitrate groups, their oxygen transfer ability.