meso-bis(1-diphenylphosphinoindenyl)iron(II)-cis-dichloropalladium(II) | 909702-88-1

• 英文名称: meso-bis(1-diphenylphosphinoindenyl)iron(II)-cis-dichloropalladium(II)
• CAS: 909702-88-1
• 化学式: C₄₂H₃₂Cl₂FeP₂Pd
• 分子量: 831.837
• InChiKey: KATOCJGJEJHGKG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 rac-bis(1-diphenylphosphinoindenyl)iron(II) 以 四氢呋喃 为溶剂， 以73%的产率得到meso-bis(1-diphenylphosphinoindenyl)iron(II)-cis-dichloropalladium(II)
  参考文献：
  名称：

  Four-coordinate complexes of bis(1-diphenylphosphinoindenyl)iron(II)

  摘要：

  Palladium, platinum and rhodiurn complexes of rac- and meso-bis(1-diphenylphosphinoindenyl)iron(II) (1) are reported. Both rac and meso isomers of {bis(1-diphenylphosphinoindenyl)iron(II)} palladium dichloride (rac- and meso-2) were characterized by X-ray crystallography along with the rac isomer of the Pt analogue (rac-3). NMR analysis of the rhodium complex [{bis(1-diphenylphosphinoindenyl)iron(II))(cyclooctadiene)rhodium(l)I tetraphenylborate suggests a similar structure in solution. Coupling reactions of n- and sec-BuCl with bromobenzene in THF are catalysed by rac-2 and found to be similar to (PPh3)(2)PdCl2 but poorer than (dppf)PdCl2 in diethyl ether. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.02.019