chlorodioxo(2-(ferrocenylmethyleneamino)ethylato)(tetrahydrofuran)molybdenum(VI) | 1178577-90-6

• 英文名称: chlorodioxo(2-(ferrocenylmethyleneamino)ethylato)(tetrahydrofuran)molybdenum(VI)
• CAS: 1178577-90-6
• 化学式: C₁₇H₂₂ClFeMoNO₄
• 分子量: 491.606
• InChiKey: UDDPSCUDEQGMCY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(二茂铁基亚甲基氨基)乙醇 、 Molybdenum, dichlorodioxobis(tetrahydrofuran)- 以 四氢呋喃 为溶剂， 以88%的产率得到chlorodioxo(2-(ferrocenylmethyleneamino)ethylato)(tetrahydrofuran)molybdenum(VI)
  参考文献：
  名称：

  Synthesis and catalytic performance for olefin epoxidation of a novel dioxomolybdenum (VI) (ferrocenylmethyleneamino)alcoholate complex

  摘要：

  A novel dioxomolybdenum (VI) complex of (ferrocenylmethyleneamino) alcoholate was easily synthesized via the reaction of MoO2Cl2(THF)(2) with N-hydroxyethyl ferrocenylimine ligand [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-CH=N-CH2-CH2-OH}], and characterized by FR-IR, H-1 NMR, UV-Vis spectroscopy and elemental analysis. In the presence of the catalytic amount of the dioxomolybdenum (VI) complex, good to excellent selectivities of epoxides (77-95%) were obtained for epoxidation of styrene and cyclohexene with tertbutyl hydroperoxide (TBHP) as oxidant in 1,2-dichloroethane at 12 h. Higher initial activity of the complex was observed for the catalyzed styrene epoxidation (451 mol mol(Mo) (1) h (1)) than that of cyclohexene epoxidation (164 mol molMo (1) h (1)) at 1 h. Meanwhile, influences of reaction temperature, solvents, reaction time as well as catalyst amount for olefin epoxidation were also investigated. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.033