[Li(THF)4]Ga2Cl4(2,4,6-(t-Bu)3C6H2) | 186599-93-9

• 英文名称: [Li(THF)4]Ga2Cl4(2,4,6-(t-Bu)3C6H2)
• CAS: 186599-93-9
• 化学式: C₁₆H₃₂LiO₄*C₁₈H₂₉Cl₄Ga₂
• 分子量: 822.055
• InChiKey: FZRXTEUVQIZAKA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Li(THF)4]Ga2Cl4(2,4,6-(t-Bu)3C6H2) 、 2,4,6-tri-tert-butylphenyllithium 以 乙醚 为溶剂， 以12%的产率得到
  参考文献：
  名称：

  Hybrid inorganic-organometallic compounds with gallium-gallium bonds

  摘要：

  The first examples of digallium compounds that feature both organo and halo substituents, [Li(THF)(4)][Ar'(Cl)GaGaCl3] (1) and Ar'(Cl)GaGa(Cl)Ar' (2), have been prepared by reaction of Ga2Cl4 . 2 dioxane with LiAr' (Ar' = 2,4,6 -(1)Bu(3)C(6)H(2)). The Ga2Cl2 skeleton of 2 is planar with a dihedral angle of 180 degrees.

  DOI：

  10.1016/s0022-328x(96)06382-6
• 作为产物：
  描述：

  、 2,4,6-tri-tert-butylphenyllithium 以 乙醚 为溶剂， 以54%的产率得到[Li(THF)4]Ga2Cl4(2,4,6-(t-Bu)3C6H2)
  参考文献：
  名称：

  Hybrid inorganic-organometallic compounds with gallium-gallium bonds

  摘要：

  The first examples of digallium compounds that feature both organo and halo substituents, [Li(THF)(4)][Ar'(Cl)GaGaCl3] (1) and Ar'(Cl)GaGa(Cl)Ar' (2), have been prepared by reaction of Ga2Cl4 . 2 dioxane with LiAr' (Ar' = 2,4,6 -(1)Bu(3)C(6)H(2)). The Ga2Cl2 skeleton of 2 is planar with a dihedral angle of 180 degrees.

  DOI：

  10.1016/s0022-328x(96)06382-6