dipyridinomethane trans-dichlorotetrafluoroosmate(IV) hydrate | 163983-17-3

• 英文名称: dipyridinomethane trans-dichlorotetrafluoroosmate(IV) hydrate
• 英文别名: N,N-methylenedipyridinium dichlorotetrafluoroosmate(IV) hydrate
• CAS: 163983-17-3
• 化学式: C₁₁H₁₂N₂*Cl₂F₄Os*H₂O
• 分子量: 527.345
• InChiKey: QLKPXVVQMCYCSJ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetra-n-butylammonium chloropentafluoroosmate(IV) 、 N,N'-methylenedipyridinium bromide 以 N,N-二甲基甲酰胺 为溶剂， 生成 dipyridinomethane trans-dichlorotetrafluoroosmate(IV) hydrate
  参考文献：
  名称：

  Dipyridiniomethane trans-Dichlorotetrafluoroosmate(IV) Hydrate, trans-[(C5H5N)2CH2][OsF4Cl2].H2O

  摘要：

  The X-ray diffraction study of dipyridiniomethane trans-dichlorotetrafluoroosmate(IV) hydrate [or N,N-methyl-enedipyridinium dichlorotetrafluoroosmate(IV) hydrate] at room temperature revealed the complete ordering of the complex anions, i.e. trans-[OsF4Cl2](2-), into AB-type salts with the doubly charged dipyridiniomethane cation [(C5H5N)(2)CH2](2+). A water molecule is linked to the F atoms by hydrogen bridges, resulting in the formation of chains. Hydrogen-bridged F atoms show Os-F distances of 1.938 (3) and 1.944 (3) Angstrom compared with non-bridged F atoms of the anion exhibiting Os-F distances of 1.924 (3) and 1.938 (3) Angstrom. The Os-Cl bond lengths are 2.341 (2) and 2.334 (2) Angstrom.

  DOI：

  10.1107/s0108270194011960