[Co2(II)(3,5-bis[bis(N-6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole-3H)][BPh4] | 1318255-14-9

• 英文名称: [Co2(II)(3,5-bis[bis(N-6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole-3H)][BPh4]
• 英文别名: [Co2(II)H2bppap][BPh4]
• CAS: 1318255-14-9
• 化学式: C₂₄H₂₀B*C₄₉H₆₃Co₂N₁₂O₄
• 分子量: 1321.34
• InChiKey: QVHPNPLPTWGSJE-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Co2(II)(3,5-bis[bis(N-6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole-3H)][BPh4] 、 水 以 丙酮 为溶剂， 生成 [(Co(II)(OH))Co(II)(3,5-bis[bis(N-6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole-2H)](1+)
  参考文献：
  名称：

  Structural Diversity in Metal Complexes with a Dinucleating Ligand Containing Carboxyamidopyridyl Groups

  摘要：

  The synthesis of a (carboxyamido)pyridinepyrazolate (H(5)bppap) dinucleating lipid is described. Bimetallic iron and cobalt complexes of Hsbppap ([M(2)(II)H(2)bppap](+)) showed structural differences in both their primary and secondary coordination spheres. The binding of small molecules into the preorganized ligand cavity is verified by the hydration of [Fe(2)(II)H(2)bppap](+) and [Co(2)(II)H(2)bppap](+), leading to the formation of complexes [{Co-II(OH)}-Co(II)H(3)bppap](+) and [{Fe-II(OH)}Fe(II)H(3)bppap](+), in which one of the metal centers has a terminal hydroxo ligand.

  DOI：

  10.1021/ic200881t
• 作为产物：
  描述：

  3,5-bis[bis(6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole 、 四苯硼钠 、 cobalt(II) acetate 在 NaOMe 作用下， 以 甲醇 为溶剂， 以86%的产率得到[Co2(II)(3,5-bis[bis(N-6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole-3H)][BPh4]
  参考文献：
  名称：

  Structural Diversity in Metal Complexes with a Dinucleating Ligand Containing Carboxyamidopyridyl Groups

  摘要：

  The synthesis of a (carboxyamido)pyridinepyrazolate (H(5)bppap) dinucleating lipid is described. Bimetallic iron and cobalt complexes of Hsbppap ([M(2)(II)H(2)bppap](+)) showed structural differences in both their primary and secondary coordination spheres. The binding of small molecules into the preorganized ligand cavity is verified by the hydration of [Fe(2)(II)H(2)bppap](+) and [Co(2)(II)H(2)bppap](+), leading to the formation of complexes [{Co-II(OH)}-Co(II)H(3)bppap](+) and [{Fe-II(OH)}Fe(II)H(3)bppap](+), in which one of the metal centers has a terminal hydroxo ligand.

  DOI：

  10.1021/ic200881t