trans-μ-diazidobis[(2,6-diisopropyl-N-(benzyliden-2-ido)aniline)palladium(II)] | 1334680-71-5

• 英文名称: trans-μ-diazidobis[(2,6-diisopropyl-N-(benzyliden-2-ido)aniline)palladium(II)]
• 英文别名: [Pd(C6H4CH=NC6H3-2,6-i-Pr2)(μ-N3)2
• CAS: 1334680-71-5
• 化学式: C₃₈H₄₄N₈Pd₂
• 分子量: 825.661
• InChiKey: WOXRADBULQPIMJ-UFBISGSOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pd(C,N-κ2-C6H4CH=NC6H3-2,6-i-Pr2)(μ-Cl)]2 、 sodium azide 以 甲醇 、 二氯甲烷 为溶剂， 以72%的产率得到trans-μ-diazidobis[(2,6-diisopropyl-N-(benzyliden-2-ido)aniline)palladium(II)]
  参考文献：
  名称：

  Facile synthesis and characterization of μ-chloro, azido, thiocyanato bridged cyclometallated Pd(II) containing Schiff-base ligands

  摘要：

  mu-Chloro bridged dinuclear cyclometallated Pd(II) complexes [Pd{(4-R)C6H3CH=NC6H3-2,6-i-Pr-2}(mu-Cl)](2) (R = H, OMe) were prepared by reaction of Na2PdCl4 with benzylideneanilines. Unexpectedly, Na2PdCl4 reacted with Schiff-bases bearing a furyl or a thienyl ring to give N-coordinated non-cyclometallated Pd(II) species [Pd(C4H3XCH=NC6H3-2,6-i-Pr-2)(2)Cl-2] (X = O, S). Treating [Pd{(4-R)C6H3CH=NC6H3-2,6-i-Pr-2}( mu-Cl)](2) (R = H, OMe) with an excess of NaN3 or NH4SCN generated mu-N-3 bridged or mu-SCN bridged cyclometallated Pd(II) complexes [Pd{(4-R)C6H3CH=NC6H3-2,6-i-Pr-2}(mu-Y)](2) (R = H, OMe; Y = N-3, NCS). The complexes were characterized by FTIR, NMR spectroscopy, elemental analysis and X-ray crystallography. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.003