{Cu5(2,4,6-trimethylphenyl)5} | 88760-64-9

• 英文名称: {Cu5(2,4,6-trimethylphenyl)5}
• 英文别名: mesityl copper(I)；mesityl copper；mesitylcopper；Cu5Mes5
• CAS: 88760-64-9
• 化学式: C₄₅H₅₅Cu₅
• 分子量: 913.662
• InChiKey: JUVCDKJKYRLRGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Cu5(2,4,6-trimethylphenyl)5} 在 六甲基苯 作用下， 以 全氘代环己烷 为溶剂， 生成 {Cu2(2,4,6-trimethylphenyl)5}
  参考文献：
  名称：

  第11组金属的多核芳基衍生物。合成，固态溶液结构关系以及与膦的反应性

  摘要：

  DOI：

  10.1021/om00106a031
• 作为产物：
  描述：

  copper(l) chloride 、 magnesium,1,3,5-trimethylbenzene-6-ide,bromide 以 四氢呋喃 为溶剂， 以65%的产率得到{Cu5(2,4,6-trimethylphenyl)5}
  参考文献：
  名称：

  第11组金属的多核芳基衍生物。合成，固态溶液结构关系以及与膦的反应性

  摘要：

  DOI：

  10.1021/om00106a031

文献信息

• Ring contraction in an arylcopper(I) compound promoted by a sulphur donor ligand : penta[mesitylcopper(I)] forms a tetra[mesitylcopper(I)] compound
  作者：Sandro Gambarotta、Carlo Floriani、Angiola Chiesi-Villa、Carlo Guastini

  DOI：10.1039/c39830001156

  日期：——

  Mesitylcopper(I)(CuMes)n was shown by an X-ray analysis to be a cyclic pentameric arylcopper(I) complex (CuMes)5 in the solid state, which undergoes ring contraction with tetrahydrothiophene to the corresponding tetrameric species [Cu4Mes4(C4H8S)2], the structure of which has been found by X-ray crystallography.

  X射线分析表明，Mesitylcopper（I）（CuMes）n是固态的环状五聚芳基铜（I）配合物（CuMes）5，它与四氢噻吩经历环收缩形成相应的四聚体物质[Cu 4 Mes 4（C 4 H 8 S）2 ]，其结构已通过X射线晶体学发现。
• Oligonuclear Homoleptic Copper(I) Pyrazolates with Multinucleating Ligand Scaffolds: High Structural Diversity in Solid-State and Solution
  作者：Michael Stollenz、Michael John、Henrike Gehring、Sebastian Dechert、Christian Grosse、Franc Meyer

  DOI：10.1021/ic900727h

  日期：2009.11.2

  assembly of linear coordinated copper(I)-centers bridged by pyrazolato ligands that alternate above and below the Cu4 plane, with additional weak interactions from some of the ligand side arms. As the single crystal X-ray structure of 3 reveals, phenyl substitution at the 4-position of the pyrazolato framework leads to significant structural modification of the Cu4 array, giving a rhombical tetranuclear

  三种基于吡唑的潜在双核配体3,5-bis（R 1 N（CH 3）CH 2）-4-R 2吡唑的合成（L 1 H：R 1 =吡啶基-2-甲基-，R 2＝ Ph；L 2 H：R 1＝ 8-喹啉基-，R 2＝ H；L 3 H：R 1＝ 8-喹啉基-，R 2＝ Ph）被描述。的反应大号1 - 3与1个当量小时。的mesitylcopper提供[Cu L ] n（1− 3）。的单晶X射线结构2示出的组件线性协调铜四核（I）-centers由pyrazolato配体桥接交替的上方和下方的Cu 4平面上，与来自一些配体的侧臂的附加的弱相互作用。为一体的单晶X射线结构3揭示，苯基取代的pyrazolato框架引线，以将Cu的显著结构修饰的4位4阵列，给具有两个一rhombical四核配合物线性协调铜（I）中心其表现出短的分子内Cu···Cu接触（2.8212（10）Å）和两个外围铜（I）中心以扭曲的四面体配
• A Schiff Base Expanded Porphyrin Macrocycle that Acts as a Versatile Binucleating Ligand for Late First-Row Transition Metals
  作者：Jonathan L. Sessler、Elisa Tomat、Tarak D. Mody、Vincent M. Lynch、Jacqueline M. Veauthier、Utkir Mirsaidov、John T. Markert

  DOI：10.1021/ic048412m

  日期：2005.4.1

  chemistry of the Schiff base polypyrrolic octaaza macrocycle 1 toward late first-row transition metals was investigated. Binuclear complexes with the divalent cations Ni(II), Cu(II), and Zn(II) and with the monovalent cation Cu(I) were prepared and characterized. Air oxidation of the Cu(I) ions in the latter complex to their divalent oxidation state resulted in a change in the coordination mode relative

  研究了席夫碱聚吡咯八氮杂大环化合物1对晚期第一行过渡金属的配位化学。制备并表征了具有二价阳离子Ni（II），Cu（II）和Zn（II）以及具有单价阳离子Cu（I）的双核配合物。后者中的Cu（I）离子在空气中氧化成其二价氧化态后，相对于大环化合物，配位模式发生了变化。
• Copper and palladium complexes with N-heterocyclic carbene ligands functionalised with carboxylate groups
  作者：Andreas A. Danopoulos、Pamela Cole、Steven P. Downing、David Pugh

  DOI：10.1016/j.jorganchem.2008.07.017

  日期：2008.10

  The new imidazolium salts functionalised with the trimethylsilyl ester group 1a-c, were easily obtained by quaternisation of alkyl- or aryl-imidazoles with trimethylsilyl bromoacetate. Salt 1a was isolated and fully characterised. It reacted with mesityl copper (Cu(5)Mes(5)) under trimethylsilyl abstraction to form the complex 2. Methanolysis of 1a-c gave good yields of the carboxylic acid functionalised imidazolium salts 3a-c. Deprotonation of the latter in liquid ammonia led to the zwitterionic imidazolium carboxylates 4a-c. Reaction of 4a with (Cu(5)Mes(5)) gave solutions from which the insoluble polymeric 5a crystallised slowly. Generation of the carboxylate-functionalised NHC in situ followed by reaction with Pd(OOCCH3)(2) gave the new complex 6a in which the NHC-carboxylate ligand is chelate bidentate. (C) 2008 Elsevier B.V. All rights reserved.
• Lopes, Cesar; Hakansson, Mikael; Jagner, Susan, New Journal of Chemistry, 1997, vol. 21, # 10, p. 1113 - 1118
  作者：Lopes, Cesar、Hakansson, Mikael、Jagner, Susan

  DOI：——

  日期：——