[μ-N-(((2,3-η1:η2)-5-methyl-2-thienyl)methyl)-η1:η1-(N)-benzylamino]hexacarbonyldiiron complex | 340146-67-0

• 英文名称: [μ-N-(((2,3-η1:η2)-5-methyl-2-thienyl)methyl)-η1:η1-(N)-benzylamino]hexacarbonyldiiron complex
• CAS: 340146-67-0
• 化学式: C₁₉H₁₃Fe₂NO₆S
• 分子量: 495.075
• InChiKey: SQMBNXXTKQWKGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [μ-N-(((1,2-η1:η2)-phenyl)methyl)-η1:η1-(N)-3-methyl-2-thienylmethylamino]hexacarbonyldiiron complex 、 [μ-N-(((2,3-η1:η2)-5-methyl-2-thienyl)methyl)-η1:η1-(N)-benzylamino]hexacarbonyldiiron complex 以 苯 为溶剂， 以91%的产率得到[μ-N-(((1,2-η1:η2)-phenyl)methyl)-η1:η1-(N)-benzylamino]hexacarbonyldiiron complex
  参考文献：
  名称：

  Ironcarbonyl complexes from N-(2-thienylmethylidene)benzylamines: endo as well as exo cyclometalation and alkyl exchange

  摘要：

  The reaction of methyl substituted N-(2-thienylmethylidene)benzylamine (1) with Fe-2(CO)(9) in benzene gives endo cyclometalated (mu-eta':eta (2)-thienyl; eta':eta'(N))hexacarbonyldiiron complexes (2 and 5), exo cyclometalated (mu-eta':eta (2)-phenyl;eta':eta'(N))hexacarbonyldiiron complexes (3 and 6) and/or imidoyl triironnonacarbonyl cluster (4), in accordance with the position of methyl substituent(s). In complex 3. the thienyl unit of the original Schiff base has been replaced by a phenyl group, which comes from the same Schiff base. The X-ray structure analyses were carried out on complexes 2a, 2b, 2c and 3a. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00616-1
• 作为产物：
  描述：

  diiron nonacarbonyl 、 5-Methyl-2-thienalbenzylamin 以 苯 为溶剂， 以28.8%的产率得到[μ-N-(((2,3-η1:η2)-5-methyl-2-thienyl)methyl)-η1:η1-(N)-benzylamino]hexacarbonyldiiron complex
  参考文献：
  名称：

  Ironcarbonyl complexes from N-(2-thienylmethylidene)benzylamines: endo as well as exo cyclometalation and alkyl exchange

  摘要：

  The reaction of methyl substituted N-(2-thienylmethylidene)benzylamine (1) with Fe-2(CO)(9) in benzene gives endo cyclometalated (mu-eta':eta (2)-thienyl; eta':eta'(N))hexacarbonyldiiron complexes (2 and 5), exo cyclometalated (mu-eta':eta (2)-phenyl;eta':eta'(N))hexacarbonyldiiron complexes (3 and 6) and/or imidoyl triironnonacarbonyl cluster (4), in accordance with the position of methyl substituent(s). In complex 3. the thienyl unit of the original Schiff base has been replaced by a phenyl group, which comes from the same Schiff base. The X-ray structure analyses were carried out on complexes 2a, 2b, 2c and 3a. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00616-1