iron(III)Cl(N,N'-bis(2-hydroxylphenyl)-o-phenylenediamine)*(acetonitrile) | 949898-79-7

• 英文名称: iron(III)Cl(N,N'-bis(2-hydroxylphenyl)-o-phenylenediamine)*(acetonitrile)
• CAS: 949898-79-7
• 化学式: C₂H₃N*C₂₀H₁₄ClFeN₂O₂
• 分子量: 446.696
• InChiKey: DKGDIXCDCGSAST-MYHDMYFSSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  iron(III) chloride hexahydrate 、 N,N'-二水杨醛缩-1,2-苯二胺 、 乙腈 以 甲醇 、 乙腈 为溶剂， 以30.2%的产率得到iron(III)Cl(N,N'-bis(2-hydroxylphenyl)-o-phenylenediamine)*(acetonitrile)
  参考文献：
  名称：

  Syntheses and Crystal Structures of Fe(III) and Mn(III) Complexes with Salen Ligands: [Fe(salen)CL] · CH₃CN and [Mn(salen)(SCN)(CH₃OH)] · CH₃CN

  摘要：

  Fe(III) and Mn(III) complexes with salen possessing appended ligands, [Fe(salen) l] center dot CH3CN(1) and [Mn(salen)(SCN)CH3OH] center dot CH3CN(2) [salen = N, N'-bis(2-hydroxylphenyl)-o-phenylenediamine], have been synthesized, and their crystal structures have been determined by X-ray diffraction analyses. The complex (1) belong to triclinic system with space group P-1, its structural unit has Fe(III) N2O2Cl configuration with distorted quadrangle pyramid geometry. The complex (2) belong to monoclinic system with space group P2(1)/c, its structural unit has MnN3O3 configuration with distorted octahedron geometry.

  DOI：

  10.1080/15533170600962604