| 1603830-89-2

• CAS: 1603830-89-2
• 化学式: C₁₆H₂₈Cl₂N₂O₂Zn
• 分子量: 416.707
• InChiKey: MVHWANXTJCKVOJ-PSASYNKPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 (3E)-3-(2,2-dimethylhydrazono)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 、 zinc(II) chloride 反应 2.0h， 以63%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and study of the catalytic properties of Zn(II) camphor derived complexes

  摘要：

  Zinc(II) complexes of general formula [ZnX2(YNC10H14O)], [ZnX2(YNC10H13NSO2)], [ZnX2(H2NNC10H14O)(2)], [{ZnX2}(2)(YNC10H14O)] and [{ZnX2}(2)(YNC10H13NSO2)] were obtained from zinc halides (chloride or bromide) by reaction with the suitable camphor ligands.In most of the complexes, the camphor ligands remain unchanged upon coordination, except in [{Zn(MeNNC10H14O)}(2)(mu-Cl)(2)] where proton loss from MeHNNC10H14O occurs. The new complexes and camphor derivatives were characterized by IR, NMR (H-1, C-13{H}, DEPT, 2D) and elemental analysis. In some cases the surface composition was studied by X-ray photoelectron spectroscopy (XPS) and imaged by Scanning Electron Microscopy (SEM). Images of [ZnCl2(Me2NNC10H14O)] and [ZnCl2(Me2NNC10H13NSO2)] obtained by SEM show the solid particles have tubular structures capped in one or both extremities. The coordination of THF in [ZnCl2(YNC10H14O) THF] was confirmed by X-ray diffraction analysis. The camphor derivatives YNC10H14NSO2 (Y = NMe2; NHMe) and p-C6H4(NC10H14O)(2) were structurally characterized by X-ray diffraction analysis.The ability of selected Zn(II) camphor complexes to catalyse the cyclization of 4-pentyn-1-ol was evaluated showing that the binuclear complex [{ZnX2}(2)(YNC10H14O)] performs better than the mononuclear Zn(II) complexes. (C) 2013 Elsevier B.V. All rights reserve.

  DOI：

  10.1016/j.jorganchem.2013.10.040