| 401798-19-4

• CAS: 401798-19-4
• 化学式: C₄₈H₄₇Cl₂FeNO₃P₂Ru
• 分子量: 975.677
• InChiKey: SYFWSEZECHZSEG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-ferrocenylphenylisocyanide 、 RuCl₂((C₆H₅)2PCH₂CH₂OCH₃)2 、 一氧化碳 以 二氯甲烷 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  Ruthenium(II) complexes containing 4-ferrocenylphenylisocyanide ligands. Crystal structure of trans, trans, trans-[RuCl2(POMeP)2(FcC6H4NC)2] (POMe=PPh2C6H4OCH3; Fc=ferrocenyl)

  摘要：

  The ruthenium complexes trans, trans, trans-[RuCl2(POMe-P)(2)(FcC(6)H(4)NC)(2)] (1) (POMe = PPh2C6H4OCH3; Fc = ferrocenyl) and trans, trans, trans -[RuCl2(PC2OMe-P)(2)(FCC6H4NC)(2)] (2) (PC2OMe = PPh2CH2CH2OCH3) have been prepared by reaction of FcC(6)H(4)NC with [RuCl2(POMe-P,O)(2)] (5) and [RuCl2(PC2OMe-P,O)(2)] (6), respectively. The mixed carbonyl-isocyanide complexes trans, trans, trans -[RuCl2(PoMe-P)(2)(Co)(FcC(6)H(4)NC)] (3) and trans, trans, trans -[RuCl2(PC2OMe-P)(2)- (CO)(FcC(6)H(4)NC)] (4) were prepared by sequential reaction of 5 and 6 with carbon monoxide and FcC(6)H(4)NC, respectively. These complexes have all been characterized by H-1-NMR, P-31-NMR and infrared spectroscopies as well as microanalysis. The solid-state structure of 1 was determined by X-ray crystallography. All three pairs of ligands are trans in this complex, and the ferrocenyl groups are tilted with respect to the phenyl ring plane by 28 degrees. Cyclic voltammetry of these complexes reveals essentially no electronic interaction occurs between the ferrocenyl groups and the Ru. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00887-7