{Ru(η-MeC6H4Prip)Cl(OC6H4CH=NCHMePh)} | 137912-48-2

• 英文名称: {Ru(η-MeC6H4Prip)Cl(OC6H4CH=NCHMePh)}
• 英文别名: [(η(6)-cymene)Ru((S)-(1-phenylethyl)salicylaldiminate)Cl]
• CAS: 137912-48-2；150576-85-5；137942-62-2
• 化学式: C₂₅H₂₈ClNORu
• 分子量: 495.026
• InChiKey: DXAIHZKCNLGDLJ-KYUUXWJZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4-甲基吡啶 、 六氟磷酸银 、 {Ru(η-MeC6H4Prip)Cl(OC6H4CH=NCHMePh)} 以 丙酮 为溶剂， 以90%的产率得到(+)D-(RRu,SC)-[(η(6)-cymene)Ru((1-phenylethyl)salicylaldiminate)(4-methylpyridine)]PF6
  参考文献：
  名称：

  Stereochemistry at the Chiral Ruthenium Atom in Half-Sandwich Compounds of the Type [(.eta.6-Ar)Ru(LL*)L']X and [(.eta.6-Ar)Ru(LL*)-Hal]. X-ray Structure Analysis of [(.eta.6-cymene)Ru(LL*)(4-Mepy)]PF6 and Appeal to the Proper Use of Stereochemical Terminology

  摘要：

  In the series of optically active half-sandwich complexes of the type [(eta(6)-Ar)Ru(LL*)L']X and [(eta(6)-Ar)-Ru(LL*)Hal] configurational assignments on the basis of the CD spectra have been made, which are unwarranted, as shown by the X-ray crystallographic analysis of (+)(D)-(R(Ru),S-C)-[(eta(6)-cymene)Ru(LL*)4-Mepy]PF6, 1. Furthermore, the configurational lability at the Ru atom in solution at room temperature and even below leads to equilibrium with respect to the metal configuration, making previous assignments of retention and inversion stereochemistry in substitution reactions meaningless.

  DOI：

  10.1021/ic00116a029
• 作为产物：
  描述：

  {Ru(η-MeC6H4Prip)(OH2)(OC6H4CH=NCHMePh)}(ClO4) 、 sodium chloride 以 丙酮 为溶剂， 生成 {Ru(η-MeC6H4Prip)Cl(OC6H4CH=NCHMePh)}
  参考文献：
  名称：

  Mandal, Sisir K.; Chakravarty, Akhil R., Inorganic Chemistry, 1993, vol. 32, # 18, p. 3851 - 3854

  摘要：

  DOI：