72-76 Valence electron clusters. An extension of the 16-18 electron rule. Synthesis, crystal structure, and solution dynamics of the trigonal-bipyramidal pentanuclear clusters [PtIr4(CO)9(.mu.-CO)5]2- and [PtIr4(CO)9(.mu.-CO)3]2-
Carbonylation chemistry of the tantalum silyl (.eta.5-C5Me5)Cl3TaSiMe3. Synthesis, characterization, and reaction chemistry of (.eta.5-C5Me5)Cl3Ta(.eta.2-COSiMe3) and derivatives
作者:John Arnold、T. Don Tilley、Arnold L. Rheingold、Steven J. Geib、Atta M. Arif